SOLVER 4592 MAXI PREP ACRYLIC UNDERCOAT
Chemwatch Independent Material Safety Data Sheet
Issue Date: 6-Dec-2007
C9317EC
CHEMWATCH 8075-72
Version No:3
SOLVER 4592 MAXI PREP ACRYLIC UNDERCOAT
"Acrylic White latex paint undercoating"
Water based, synthetic resin primer/undercoat.
Company: Solver Paints Pty Ltd Address: 560 Churchill Road Kilburn SA, 5084 Australia Telephone: +61 8 8368 1200 Emergency Tel: 1800 039 008 (24 hours) Emergency Tel: +61 3 9573 3112 Fax: +61 8 8368 1222
NON-HAZARDOUS SUBSTANCE. NON-DANGEROUS GOODS. According to NOHSC Criteria, and ADG Code.
None
Risk Codes Risk Phrases R52 ■ Harmful to aquatic organisms.
Safety Codes Safety Phrases S23 ■ Do not breathe gas/fumes/vapour/spray. S24 ■ Avoid contact with skin. S39 ■ Wear eye/face protection. S51 ■ Use only in well ventilated areas. S09 ■ Keep container in a well ventilated place. S07 ■ Keep container tightly closed. S26 ■ In case of contact with eyes rinse with plenty of water and contact Doctor or Poisons Information Centre.
| NAME | CAS RN | % |
| acrylic polymer emulsion | 10-30 | |
| acrylic resin | Various | 10-30 |
| titanium dioxide | 13463-67-7 | 10-30 |
| extender | 10-30 | |
| ammonium hydroxide | 1336-21-6 | <0.1 |
| additives unregulated | 1-9 | |
| water | 7732-18-5 | 10-30 |
· Immediately give a glass of water.
· First aid is not generally required. If in doubt, contact a Poisons Information Centre or a doctor.
■ If this product comes in contact with the eyes:
· Wash out immediately with fresh running water.
· Ensure complete irrigation of the eye by keeping eyelids apart and away from eye and moving the eyelids by occasionally lifting the upper and lower lids.
· Seek medical attention without delay; if pain persists or recurs seek medical attention.
· Removal of contact lenses after an eye injury should only be undertaken by skilled personnel.
■ If skin contact occurs:
· Immediately remove all contaminated clothing, including footwear.
· Flush skin and hair with running water (and soap if available).
· Seek medical attention in event of irritation.
· If fumes or combustion products are inhaled remove from contaminated area.
· Other measures are usually unnecessary.
■ Treat symptomatically.
· There is no restriction on the type of extinguisher which may be used. · Use extinguishing media suitable for surrounding area.
· Alert Fire Brigade and tell them location and nature of hazard. · Wear breathing apparatus plus protective gloves for fire only. · Prevent, by any means available, spillage from entering drains or water courses. · Use fire fighting procedures suitable for surrounding area.
· Non combustible. · Not considered a significant fire risk, however containers may burn. Decomposition may produce toxic fumes of: carbon dioxide (CO2), other pyrolysis products typical of burning organic material. May emit poisonous fumes. May emit corrosive fumes.
· Avoid contamination with oxidising agents i.e. nitrates, oxidising acids, chlorine bleaches, pool chlorine etc. as ignition may result.
None
| Glasses: | Gloves: | Respirator: |
| Safety Glasses. | PVC chemical resistant type. | Type K Filter of sufficient capacity |
· Clean up all spills immediately. · Avoid breathing vapours and contact with skin and eyes. · Control personal contact by using protective equipment. · Contain and absorb spill with sand, earth, inert material or vermiculite.
■ Moderate hazard. · Clear area of personnel and move upwind. · Alert Fire Brigade and tell them location and nature of hazard. · Wear breathing apparatus plus protective gloves. · Prevent, by any means available, spillage from entering drains or water course.
Personal Protective Equipment advice is contained in Section 8 of the MSDS.
· Avoid all personal contact, including inhalation.
· Wear protective clothing when risk of exposure occurs.
· Use in a well-ventilated area.
· Avoid contact with moisture.
· DO NOT allow clothing wet with material to stay in contact with skin.
· Polyethylene or polypropylene container.
· Packing as recommended by manufacturer.
· Check all containers are clearly labelled and free from leaks.
· Avoid reaction with oxidising agents.
· Store in original containers.
· Keep containers securely sealed.
· Store in a cool, dry, well-ventilated area.
· Store away from incompatible materials and foodstuff containers.
| Source | Material | TWA ppm | TWA mg/m³ | STEL ppm | STEL mg/m³ | Notes |
| ___________ | ___________ | _______ | _______ | _______ | _______ | _______ |
| Australia Exposure Standards | titanium dioxide (Titanium dioxide (a)) | 10 | (see Chapter 14) | |||
| Australia Exposure Standards | ammonium hydroxide (Ammonia) | 25 | 17 | 35 | 24 |
The following materials had no OELs on our records
| • water: | CAS:7732-18-5 |
Type K Filter of sufficient capacity
· Safety glasses with side shields. · Chemical goggles. · Contact lenses may pose a special hazard; soft contact lenses may absorb and concentrate irritants. A written policy document, describing the wearing of lens or restrictions on use, should be created for each workplace or task. This should include a review of lens absorption and adsorption for the class of chemicals in use and an account of injury experience. Medical and first- aid personnel should be trained in their removal and suitable equipment should be readily available. In the event of chemical exposure, begin eye irrigation immediately and remove contact lens as soon as practicable. Lens should be removed at the first signs of eye redness or irritation - lens should be removed in a clean environment only after workers have washed hands thoroughly. [CDC NIOSH Current Intelligence Bulletin 59].
· Wear chemical protective gloves, eg. PVC. · Wear safety footwear or safety gumboots, eg. Rubber.
· Overalls. · P.V.C. apron. · Barrier cream. · Skin cleansing cream.
■ General exhaust is adequate under normal operating conditions. Local exhaust ventilation may be required in specific circumstances.
White liquid paint with a mild odour; mixes with water.
Liquid.
Mixes with water.
| State | Liquid | Molecular Weight | Not applicable |
| Melting Range (ºC) | Not available. | Viscosity | Not available |
| Boiling Range (ºC) | >100 | Solubility in water (g/L) | Miscible |
| Flash Point (ºC) | None | pH (1% solution) | Not available |
| Decomposition Temp (ºC) | Not available. | pH (as supplied) | 8-10 |
| Autoignition Temp (ºC) | Not applicable | Vapour Pressure (kPa) | <1 |
| Upper Explosive Limit (%) | Not applicable | Specific Gravity (water=1) | 1.35-1.40 |
| Lower Explosive Limit (%) | Not applicable | Relative Vapour Density (air=1) | Not available. |
| Volatile Component (%vol) | 35-40 | Evaporation Rate | Slow |
· Presence of incompatible materials.
· Product is considered stable.
· Hazardous polymerisation will not occur.
For incompatible materials - refer to Section 7 - Handling and Storage.
| ACUTE HEALTH EFFECTS | CHRONIC HEALTH EFFECTS |
| ■ Not applicable. | ■ Not applicable. |
AMMONIUM HYDROXIDE: TITANIUM DIOXIDE: ■ unless otherwise specified data extracted from RTECS - Register of Toxic Effects of Chemical Substances. ■ None assigned. Refer to individual constituents. ACRYLIC RESIN: ■ No data of toxicological significance identified in literature search. CAUTION: The chronic health effects of acrylic monomers are under review. Use good occupational work practices to avoid personal contact. TITANIUM DIOXIDE:
| TOXICITY | IRRITATION |
| Oral (Rat) LD50: >20000 mg/kg * | Skin (human): 0.3 mg /3D (int)-Mild * |
| Oral (Mouse) LD50: >10000 mg/kg * |
| TOXICITY | IRRITATION |
| Oral (rat) LD50: 350 mg/kg | Eye (rabbit): 0.25 mg SEVERE |
| Oral (human) LDLo: 43 mg/kg | Eye (rabbit): 1 mg/30s SEVERE |
| Inhalation (human) LCLo: 5000 ppm/5m | |
| Inhalation (human) TCLo: 20 ppm | |
| Inhalation (rat) LC50: 2000 ppm/4h | |
| Unreported (man) LDLo: 132 mg/kg |
| Titanium dioxide | International Agency for Research on Cancer (IARC) - Agents Reviewed by the IARC Monographs | Group | 2B |
Harmful to aquatic organisms.
| Ingredient | Persistence: Water/Soil | Persistence: Air | Bioaccumulation | Mobility |
| titanium dioxide | HIGH | LOW | HIGH | |
| ammonium hydroxide | LOW | LOW | HIGH | |
| water | LOW | LOW | HIGH |
· Recycle wherever possible.
· Consult manufacturer for recycling options or consult local or regional waste management authority for disposal if no suitable treatment or disposal facility can be identified.
· Dispose of by: burial in a land-fill specifically licenced to accept chemical and / or pharmaceutical wastes or incineration in a licenced apparatus (after admixture with suitable combustible material).
· Decontaminate empty containers. Observe all label safeguards until containers are cleaned and destroyed.
· Containers may still present a chemical hazard/ danger when empty.
· Return to supplier for reuse/ recycling if possible.
Otherwise:
· If container can not be cleaned sufficiently well to ensure that residuals do not remain or if the container cannot be used to store the same product, then puncture containers, to prevent re-use, and bury at an authorised landfill.
· Where possible retain label warnings and MSDS and observe all notices pertaining to the product.
None (ADG7) NOT REGULATED FOR TRANSPORT OF DANGEROUS GOODS: ADG7, UN, IATA, IMDG
None
Regulations for ingredients
"Australia Exposure Standards","Australia High Volume Industrial Chemical List (HVICL)","Australia Inventory of Chemical Substances (AICS)","Australia Therapeutic Goods Administration (TGA) Substances that may be used as active ingredients in Listed medicines","Australia Therapeutic Goods Administration (TGA) Sunscreening agents permitted as active ingredients in listed products","CODEX General Standard for Food Additives (GSFA) - Additives Permitted for Use in Food in General, Unless Otherwise Specified, in Accordance with GMP","GESAMP/EHS Composite List - GESAMP Hazard Profiles","IMO IBC Code Chapter 17: Summary of minimum requirements","International Agency for Research on Cancer (IARC) - Agents Reviewed by the IARC Monographs","OECD Representative List of High Production Volume (HPV) Chemicals"
"Australia Hazardous Substances","Australia Inventory of Chemical Substances (AICS)","Australia Standard for the Uniform Scheduling of Drugs and Poisons (SUSDP) - Appendix F (Part 3)","CODEX General Standard for Food Additives (GSFA) - Additives Permitted for Use in Food in General, Unless Otherwise Specified, in Accordance with GMP","IMO MARPOL 73/78 (Annex II) - List of Noxious Liquid Substances Carried in Bulk","International Council of Chemical Associations (ICCA) - High Production Volume List","OECD Representative List of High Production Volume (HPV) Chemicals"
"Australia Inventory of Chemical Substances (AICS)","IMO IBC Code Chapter 18: List of products to which the Code does not apply","OECD Representative List of High Production Volume (HPV) Chemicals"
No data for acrylic resin (CAS: , Various)
| Ingredient Name | CAS |
| titanium dioxide | 13463-67-7, 1317-70-0, 1317-80-2, 12188-41-9, 1309-63-3, 100292-32-8, 101239-53-6, 116788-85-3, 12000-59-8, 12701-76-7, 12767-65-6, 12789-63-8, 1344-29-2, 185323-71-1, 185828-91-5, 188357-76-8, 188357-79-1, 195740-11-5, 221548-98-7, 224963-00-2, 246178-32-5, 252962-41-7, 37230-92-5, 37230-94-7, 37230-95-8, 37230-96-9, 39320-58-6, 39360-64-0, 39379-02-7, 416845-43-7, 494848-07-6, 494848-23-6, 494851-77-3, 494851-98-8, 55068-84-3, 55068-85-4, 552316-51-5, 62338-64-1, 767341-00-4, 97929-50-5, 98084-96-9 |
■ Classification of the preparation and its individual components has drawn on official and authoritative sources as well as independent review by the Chemwatch Classification committee using available literature references.
A list of reference resources used to assist the committee may be found at:
www.chemwatch.net/references.
■ The (M)SDS is a Hazard Communication tool and should be used to assist in the Risk Assessment. Many factors determine whether the reported Hazards are Risks in the workplace or other settings.
This document is copyright. Apart from any fair dealing for the purposes of private study, research, review or
criticism, as permitted under the Copyright Act, no part may be reproduced by any process without written
permission from CHEMWATCH. TEL (+61 3) 9572 4700.
Issue Date: 6-Dec-2007
Print Date: 24-Aug-2010
This is the end of the MSDS.