Section 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

PRODUCT NAME

SOLVER 4144 BRITE GLO LOW SHEEN ACRYLIC VICTORIA BLUE

SYNONYMS

"sign signwriters water paint"

PRODUCT USE

• Apply by brush, hand roller or spray atomisation.
A water reducible low sheen, high opacity sign paint.

SUPPLIER

Company: Solver Paints Pty Ltd          
Address:                                
560 Churchill Road                      
Kilburn                                 
SA, 5084                                
Australia                               
Telephone: +61 8 8368 1200              
Emergency Tel: 1800 039 008 (24 hours)  
Emergency Tel: +61 3 9573 3112          
Fax: +61 8 8368 1222                    
                                        

Section 2 - HAZARDS IDENTIFICATION

STATEMENT OF HAZARDOUS NATURE

NON-HAZARDOUS SUBSTANCE. NON-DANGEROUS GOODS. According to NOHSC Criteria, and ADG Code.

POISONS SCHEDULE

None

RISK

•None under normal operating conditions.

SAFETY

Safety Codes          Safety Phrases
S23                   • Do not breathe gas/fumes/vapour/spray.
S24                   • Avoid contact with skin.
S39                   • Wear eye/face protection.
S26                   • In case of contact with eyes rinse with plenty of water
                      and contact Doctor or Poisons Information Centre.

Section 3 - COMPOSITION / INFORMATION ON INGREDIENTS

Section 4 - FIRST AID MEASURES

SWALLOWED

· Immediately give a glass of water.
· First aid is not generally required. If in doubt, contact a Poisons Information Centre or a doctor.

EYE

• If this product comes in contact with the eyes:
· Wash out immediately with fresh running water.
· Ensure complete irrigation of the eye by keeping eyelids apart and away from eye and moving the eyelids by occasionally lifting the upper and lower lids.
· Seek medical attention without delay; if pain persists or recurs seek medical attention.
· Removal of contact lenses after an eye injury should only be undertaken by skilled personnel.

SKIN

• If skin contact occurs:
· Immediately remove all contaminated clothing, including footwear.
· Flush skin and hair with running water (and soap if available).
· Seek medical attention in event of irritation.

INHALED

· If fumes or combustion products are inhaled remove from contaminated area.
· Other measures are usually unnecessary.

NOTES TO PHYSICIAN

• Treat symptomatically.

Section 5 - FIRE FIGHTING MEASURES

EXTINGUISHING MEDIA

· There is no restriction on the type of extinguisher which may be used.
· Use extinguishing media suitable for surrounding area.

FIRE FIGHTING

· Alert Fire Brigade and tell them location and nature of hazard.
· Wear breathing apparatus plus protective gloves for fire only.
· Prevent, by any means available, spillage from entering drains or water courses.
· Use fire fighting procedures suitable for surrounding area.

FIRE/EXPLOSION HAZARD

· Non combustible.
· Not considered a significant fire risk, however containers may burn.
Decomposition may produce toxic fumes of: nitrogen oxides (NOx).

FIRE INCOMPATIBILITY

• None known.

HAZCHEM

None

PERSONAL PROTECTION

Glasses:           
Gloves:                       
Respirator:                              
Chemical goggles.  
PVC chemical resistant type.  
Type AK-P Filter of sufficient capacity  

Section 6 - ACCIDENTAL RELEASE MEASURES

MINOR SPILLS

· Clean up all spills immediately.
· Avoid breathing vapours and contact with skin and eyes.
· Control personal contact by using protective equipment.
· Contain and absorb spill with sand, earth, inert material or vermiculite.

MAJOR SPILLS

• Moderate hazard.
· Clear area of personnel and move upwind.
· Alert Fire Brigade and tell them location and nature of hazard.
· Wear breathing apparatus plus protective gloves.
· Prevent, by any means available, spillage from entering drains or water course.

Personal Protective Equipment advice is contained in Section 8 of the MSDS.

Section 7 - HANDLING AND STORAGE

PROCEDURE FOR HANDLING

· DO NOT allow clothing wet with material to stay in contact with skin.
· Avoid all personal contact, including inhalation.
· Wear protective clothing when risk of exposure occurs.
· Use in a well-ventilated area.
· Avoid contact with moisture.

SUITABLE CONTAINER

· Polyethylene or polypropylene container.
· Packing as recommended by manufacturer.
· Check all containers are clearly labelled and free from leaks.

STORAGE INCOMPATIBILITY

• None known.

STORAGE REQUIREMENTS

· Store in original containers.
· Keep containers securely sealed.
· Store in a cool, dry, well-ventilated area.
· Store away from incompatible materials and foodstuff containers.

Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION

EXPOSURE CONTROLS

  • 2,2,4-trimethyl-1,3-pentanediol monoisobutyrate: 
 CAS:25265-77-4 CAS:77-68-9
  • 1,2-benzisothiazoline-3-one: 
 CAS:2634-33-5
  • 2-methyl-4-isothiazolin-3-one: 
 CAS:2682-20-4

PERSONAL PROTECTION

RESPIRATOR

Type AK-P Filter of sufficient capacity

EYE

· Safety glasses with side shields.
· Chemical goggles.
· Contact lenses may pose a special hazard; soft contact lenses may absorb and concentrate irritants. A written policy document, describing the wearing of lens or restrictions on use, should be created for each workplace or task. This should include a review of lens absorption and adsorption for the class of chemicals in use and an account of injury experience. Medical and first-aid personnel should be trained in their removal and suitable equipment should be readily available. In the event of chemical exposure, begin eye irrigation immediately and remove contact lens as soon as practicable. Lens should be removed at the first signs of eye redness or irritation - lens should be removed in a clean environment only after workers have washed hands thoroughly. [CDC NIOSH Current Intelligence Bulletin 59].

HANDS/FEET

· Wear chemical protective gloves, eg. PVC.
· Wear safety footwear or safety gumboots, eg. Rubber.
Suitability and durability of glove type is dependent on usage. Important factors in the selection of gloves include: such as:
· frequency and duration of contact,
· chemical resistance of glove material,
· glove thickness and
· dexterity.

OTHER

· Overalls.
· P.V.C. apron.
· Barrier cream.
· Skin cleansing cream.

ENGINEERING CONTROLS

• General exhaust is adequate under normal operating conditions. Local exhaust ventilation may be required in specific circumstances.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES

APPEARANCE

• Acrylic polymer emulsions may contain residual traces of odourous acrylic monomers; the amounts remaining in compounded mixtures represents a very low order of exposure, however this may become noticeable with some materials particularly in confined or poorly ventilated spaces.
Blue liquid with a mild ammonia/acrylic paint odour; miscible with water.

PHYSICAL PROPERTIES

Liquid.
Mixes with water.

State
Liquid
Molecular Weight
Not applicable
Melting Range (ºC)
Not available.
Viscosity
Not Available
Boiling Range (ºC)
100 water.
Solubility in water (g/L)
Miscible
Flash Point (ºC)
Non Flammable
pH (1% solution)
Not applicable
Decomposition Temp (ºC)
Not available.
pH (as supplied)
10
Autoignition Temp (ºC)
Not applicable
Vapour Pressure (kPa)
As water
Upper Explosive Limit (%)
Not applicable
Specific Gravity (water=1)
1.16
Lower Explosive Limit (%)
Not applicable
Relative Vapour Density (air=1)
Not available.
Volatile Component (%vol)
55 approx.
Evaporation Rate
Slow

Section 10 - CHEMICAL STABILITY AND REACTIVITY INFORMATION

CONDITIONS CONTRIBUTING TO INSTABILITY

· Presence of incompatible materials.
· Product is considered stable.
· Hazardous polymerisation will not occur.

For incompatible materials - refer to Section 7 - Handling and Storage.

Section 11 - TOXICOLOGICAL INFORMATION

POTENTIAL HEALTH EFFECTS

ACUTE HEALTH EFFECTS  
CHRONIC HEALTH EFFECTS  
• Not applicable.     
• Not applicable.       

TOXICITY AND IRRITATION

• Not available. Refer to individual constituents.

ACRYLIC COPOLYMER LATEX:
• No significant acute toxicological data identified in literature search.

2,2,4-TRIMETHYL-1,3-PENTANEDIOL MONOISOBUTYRATE:
• unless otherwise specified data extracted from RTECS - Register of Toxic Effects of Chemical Substances.


TOXICITY                                 
IRRITATION                  
Oral (rat) LD50: 3200 mg/kg              
Skin - Slight Irritant *    
Oral (rat) LD50: 3200 mg/kg ***          
Skin (rabbit): Mild ***     
Dermal (rabbit) LD50: >16 ml/kg *        
Eyes - Moderate Irritant *  
Dermal (g.pig) LD50: >16 ml/kg ***       
                            
Inhalation (rat) LC50: >3.55 mg/l/6h     
                            
Inhalation (rat) LC50: 1600 mg/kg ***    
                            
Oral (Mouse) LD50: 3200 mg/kg            
                            
Dermal (None) Guinea: pig LD50>20 ml/kg  
                            

• The material may be irritating to the eye, with prolonged contact causing inflammation. Repeated or prolonged exposure to irritants may produce conjunctivitis.
The material may cause skin irritation after prolonged or repeated exposure and may produce a contact dermatitis (nonallergic). This form of dermatitis is often characterised by skin redness (erythema) and swelling epidermis.
Not a skin sensitiser (guinea pig, Magnusson-Kligman) ***
Ames Test: negative ***
Micronucleus, mouse: negative ***
Not mutagenic ***
No effects on fertility or foetal development seen in the rat ***
*  [SWIFT]
** [Eastman]
*** [Perstop]

Section 12 - ECOLOGICAL INFORMATION

No data

Ecotoxicity

Ingredient
Persistence: Water/Soil
Persistence: Air
Bioaccumulation
Mobility
2,2,4-trimethyl-1,3-pentanediol monoisobutyrate
LOW
LOW
HIGH
2-methyl-4-isothiazolin-3-one
HIGH
LOW
HIGH

Section 13 - DISPOSAL CONSIDERATIONS

· Recycle wherever possible.
· Consult manufacturer for recycling options or consult local or regional waste management authority for disposal if no suitable treatment or disposal facility can be identified.
· Dispose of by: burial in a land-fill specifically licenced to accept chemical and / or pharmaceutical wastes or incineration in a licenced apparatus (after admixture with suitable combustible material).
· Decontaminate empty containers. Observe all label safeguards until containers are cleaned and destroyed.

Section 14 - TRANSPORTATION INFORMATION

HAZCHEM:

None  (ADG7)


NOT REGULATED FOR TRANSPORT OF DANGEROUS GOODS: ADG7, UN, IATA, IMDG

Section 15 - REGULATORY INFORMATION

POISONS SCHEDULE

None

REGULATIONS

Regulations for ingredients

2,2,4-trimethyl-1,3-pentanediol monoisobutyrate (CAS: 25265-77-4,77-68-9) is found on the following regulatory lists;

"Australia High Volume Industrial Chemical List (HVICL)","Australia Inventory of Chemical Substances (AICS)","GESAMP/EHS Composite List - GESAMP Hazard Profiles","IMO IBC Code Chapter 17: Summary of minimum requirements","IMO MARPOL 73/78 (Annex II) - List of Noxious Liquid Substances Carried in Bulk","OECD Representative List of High Production Volume (HPV) Chemicals"

1,2-benzisothiazoline-3-one (CAS: 2634-33-5) is found on the following regulatory lists;

"Australia Hazardous Substances","Australia Inventory of Chemical Substances (AICS)","OECD Representative List of High Production Volume (HPV) Chemicals"

2-methyl-4-isothiazolin-3-one (CAS: 2682-20-4) is found on the following regulatory lists;

"Australia Inventory of Chemical Substances (AICS)"

No data for Solver 4144 Brite Glo Low Sheen Acrylic Victoria Blue (CW: 57758)

No data for acrylic copolymer latex (CAS: , Not avail)

Section 16 - OTHER INFORMATION

Denmark Advisory list for selfclassification of dangerous substances

Substance                                 CAS           Suggested codes
2, 2, 4- trimethyl- 1, 3- pentanediol     25265- 77- 4  N R50
monoisobutyrate
2, 2, 4- trimethyl- 1, 3- pentanediol     77- 68- 9     N R50
monoisobutyrate
2- methyl- 4- isothiazolin- 3- one        2682- 20- 4

INGREDIENTS WITH MULTIPLE CAS NUMBERS

Ingredient Name                                  
CAS                   
2,2,4-trimethyl-1,3-pentanediol monoisobutyrate  
25265-77-4,  77-68-9  

• Classification of the preparation and its individual components has drawn on official and authoritative sources as well as independent review by the Chemwatch Classification committee using available literature references.
A list of reference resources used to assist the committee may be found at:
www.chemwatch.net/references.

• The (M)SDS is a Hazard Communication tool and should be used to assist in the Risk Assessment. Many factors determine whether the reported Hazards are Risks in the workplace or other settings.

This document is copyright. Apart from any fair dealing for the purposes of private study, research, review or
criticism, as permitted under the Copyright Act, no part may be reproduced by any process without written
permission from CHEMWATCH. TEL (+61 3) 9572 4700.

Issue Date: 31-Dec-2007

Print Date: 6-Aug-2010

This is the end of the MSDS.