SOLVER 4595 MAXI CEILING PAINT

Chemwatch Independent Material Safety Data Sheet

Issue Date: 2-Jul-2008

C9317EC

CHEMWATCH 5131-58

Version No:4

Section 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

PRODUCT NAME

SOLVER 4595 MAXI CEILING PAINT

PRODUCT USE

■ Used according to manufacturer's directions.

SUPPLIER

Company: Solver Paints Pty Ltd
Address:
560 Churchill Road
Kilburn
SA, 5084
Australia
Telephone: +61 8 8368 1200
Emergency Tel: 1800 039 008 (24 hours)
Emergency Tel: +61 3 9573 3112
Fax: +61 8 8368 1222

Section 2 - HAZARDS IDENTIFICATION

STATEMENT OF HAZARDOUS NATURE

NON-HAZARDOUS SUBSTANCE. NON-DANGEROUS GOODS. According to NOHSC Criteria, and ADG Code.

POISONS SCHEDULE

None

 

RISK

•None under normal operating conditions.

SAFETY

Safety Codes Safety Phrases
S23 ■ Do not breathe gas/fumes/vapour/spray.
S24 ■ Avoid contact with skin.

 

Section 3 - COMPOSITION / INFORMATION ON INGREDIENTS

NAME CAS RN %
acrylic polymer latex Not avail. 10-30
filler as 10-30
calcium carbonate 471-34-1
titanium dioxide 13463-67-7 1-9
2, 2, 4- trimethyl- 1, 3- pentanediol monoisobutyrate 25265-77-4 <2
ingredients not contributing to the classification 10-30
water 7732-18-5 10-30

Section 4 - FIRST AID MEASURES

SWALLOWED

· Immediately give a glass of water.
· First aid is not generally required. If in doubt, contact a Poisons Information Centre or a doctor.

EYE

■ If this product comes in contact with eyes:
· Wash out immediately with water.
· If irritation continues, seek medical attention.
· Removal of contact lenses after an eye injury should only be undertaken by skilled personnel.

SKIN

■ If skin or hair contact occurs:
· Flush skin and hair with running water (and soap if available).
· Seek medical attention in event of irritation.

INHALED

· If fumes or combustion products are inhaled remove from contaminated area.
· Other measures are usually unnecessary.

NOTES TO PHYSICIAN

■ Treat symptomatically.

Section 5 - FIRE FIGHTING MEASURES

EXTINGUISHING MEDIA

· There is no restriction on the type of extinguisher which may be used.
· Use extinguishing media suitable for surrounding area.

FIRE FIGHTING

· Alert Fire Brigade and tell them location and nature of hazard.
· Wear breathing apparatus plus protective gloves for fire only.
· Prevent, by any means available, spillage from entering drains or water courses.
· Use fire fighting procedures suitable for surrounding area.

FIRE/EXPLOSION HAZARD

· Non combustible.
· Not considered a significant fire risk, however containers may burn.
Decomposition may produce toxic fumes of: carbon dioxide (CO2), other pyrolysis products typical of burning organic material.

FIRE INCOMPATIBILITY

· Avoid contamination with oxidising agents i.e. nitrates, oxidising acids, chlorine bleaches, pool chlorine etc. as ignition may result.

HAZCHEM

None

PERSONAL PROTECTION

Glasses: Gloves: Respirator:
Chemical goggles. PVC chemical resistant type. Type A Filter of sufficient capacity

Section 6 - ACCIDENTAL RELEASE MEASURES

MINOR SPILLS

· Clean up all spills immediately.
· Avoid breathing vapours and contact with skin and eyes.
· Control personal contact by using protective equipment.
· Contain and absorb spill with sand, earth, inert material or vermiculite.

MAJOR SPILLS

■ Moderate hazard.
· Clear area of personnel and move upwind.
· Alert Fire Brigade and tell them location and nature of hazard.
· Wear breathing apparatus plus protective gloves.
· Prevent, by any means available, spillage from entering drains or water course.

 

Personal Protective Equipment advice is contained in Section 8 of the MSDS.

Section 7 - HANDLING AND STORAGE

PROCEDURE FOR HANDLING

· Avoid all personal contact, including inhalation.
· Wear protective clothing when risk of exposure occurs.
· Use in a well-ventilated area.
· Prevent concentration in hollows and sumps.

SUITABLE CONTAINER

· Polyethylene or polypropylene container.
· Packing as recommended by manufacturer.
· Check all containers are clearly labelled and free from leaks.

STORAGE INCOMPATIBILITY

· Avoid reaction with oxidising agents.

STORAGE REQUIREMENTS

· Store in original containers.
· Keep containers securely sealed.
· Store in a cool, dry, well-ventilated area.
· Store away from incompatible materials and foodstuff containers.

Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION

EXPOSURE CONTROLS

SourceMaterialTWA mg/m³Notes
____________________________________
Australia Exposure Standardscalcium carbonate (Calcium carbonate (a))10(see Chapter 14)
Australia Exposure Standardstitanium dioxide (Titanium dioxide (a))10(see Chapter 14)
The following materials had no OELs on our records
• 2,2,4-trimethyl-1,3-pentanediol monoisobutyrate: CAS:25265-77-4 CAS:77-68-9
• water: CAS:7732-18-5

 

 

PERSONAL PROTECTION

RESPIRATOR

Type A Filter of sufficient capacity

EYE

· Safety glasses with side shields
· Chemical goggles.
· Contact lenses may pose a special hazard; soft contact lenses may absorb and concentrate irritants. A written policy document, describing the wearing of lens or
restrictions on use, should be created for each workplace or task. This should include a review of lens absorption and adsorption for the class of chemicals in use
and an account of injury experience. Medical and first- aid personnel should be trained in their removal and suitable equipment should be readily available. In the
event of chemical exposure, begin eye irrigation immediately and remove contact lens as soon as practicable. Lens should be removed at the first signs of eye redness
or irritation - lens should be removed in a clean environment only after workers have washed hands thoroughly. [CDC NIOSH Current Intelligence Bulletin 59].

HANDS/FEET

· Wear chemical protective gloves, eg. PVC.
· Wear safety footwear or safety gumboots, eg. Rubber.

OTHER

· Overalls.
· P.V.C. apron.
· Barrier cream.
· Skin cleansing cream.

ENGINEERING CONTROLS

■ General exhaust is adequate under normal operating conditions. If risk of overexposure exists, wear SAA approved respirator.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES

APPEARANCE

Coloured liquid with an acrylic odour; mixes with water.

PHYSICAL PROPERTIES

Liquid.
Mixes with water.

 

StateLiquidMolecular WeightNot Available
Melting Range (ºC)Not AvailableViscosityNot Available
Boiling Range (ºC)100-244Solubility in water (g/L)Miscible
Flash Point (ºC)Not ApplicablepH (1% solution)Not Available
Decomposition Temp (ºC)Not AvailablepH (as supplied)Not Available
Autoignition Temp (ºC)Not AvailableVapour Pressure (kPa)Not Available
Upper Explosive Limit (%)Not AvailableSpecific Gravity (water=1)1.30-1.35
Lower Explosive Limit (%)Not AvailableRelative Vapour Density (air=1)Not Available
Volatile Component (%vol)Not AvailableEvaporation RateNot Available

 

Section 10 - CHEMICAL STABILITY AND REACTIVITY INFORMATION

CONDITIONS CONTRIBUTING TO INSTABILITY

· Presence of incompatible materials.
· Product is considered stable.
· Hazardous polymerisation will not occur.

For incompatible materials - refer to Section 7 - Handling and Storage.

Section 11 - TOXICOLOGICAL INFORMATION

POTENTIAL HEALTH EFFECTS

ACUTE HEALTH EFFECTS CHRONIC HEALTH EFFECTS
■ Not applicable. ■ Not applicable.

TOXICITY AND IRRITATION

2, 2, 4- TRIMETHYL- 1, 3- PENTANEDIOL MONOISOBUTYRATE:
TITANIUM DIOXIDE:
■ unless otherwise specified data extracted from RTECS - Register of Toxic Effects of Chemical Substances.
■ The material may cause skin irritation after prolonged or repeated exposure and may produce a contact dermatitis (nonallergic). This form of dermatitis is often
characterised by skin redness (erythema) and swelling epidermis.
■ Not available. Refer to individual constituents.
ACRYLIC POLYMER LATEX:
TOXICITY IRRITATION
Oral (rat) LD50: >5000 mg/kg [Manfr.RH]
■ Acrylic polymer emulsions may contain residual traces of odourous acrylic monomers; the amounts remaining in compounded mixtures represents a very low order of exposure, however this may become noticeable with some materials particularly in confined or poorly ventilated spaces. TITANIUM DIOXIDE:
TOXICITY IRRITATION
Oral (Rat) LD50: >20000 mg/kg * Skin (human): 0.3 mg /3D (int)-Mild *
Oral (Mouse) LD50: >10000 mg/kg *
■ The material may produce moderate eye irritation leading to inflammation. Repeated or prolonged exposure to irritants may produce conjunctivitis. For titanium dioxide: Humans can be exposed to titanium dioxide via inhalation, ingestion or dermal contact. In human lungs, the clearance kinetics of titanium dioxide is poorly characterized relative to that in experimental animals. * IUCLID 2, 2, 4- TRIMETHYL- 1, 3- PENTANEDIOL MONOISOBUTYRATE:
TOXICITY IRRITATION
Oral (rat) LD50: 3200 mg/kg Skin - Slight Irritant *
Oral (rat) LD50: 3200 mg/kg *** Skin (rabbit): Mild ***
Dermal (rabbit) LD50: >16 ml/kg * Eyes - Moderate Irritant *
Dermal (g.pig) LD50: >16 ml/kg ***
Inhalation (rat) LC50: >3.55 mg/l/6h
Inhalation (rat) LC50: 1600 mg/kg ***
Oral (Mouse) LD50: 3200 mg/kg
Dermal (None) Guinea: pig LD50>20 ml/kg
■ The material may be irritating to the eye, with prolonged contact causing inflammation. Repeated or prolonged exposure to irritants may produce conjunctivitis. Not a skin sensitiser (guinea pig, Magnusson- Kligman) *** Ames Test: negative *** Micronucleus, mouse: negative *** Not mutagenic *** No effects on fertility or foetal development seen in the rat *** * [SWIFT] ** [Eastman] *** [Perstop] WATER: ■ No significant acute toxicological data identified in literature search.

 

CARCINOGEN

Titanium dioxideInternational Agency for Research on Cancer (IARC) - Agents Reviewed by the IARC MonographsGroup2B

 

Section 12 - ECOLOGICAL INFORMATION

No data

Ecotoxicity

IngredientPersistence: Water/SoilPersistence: AirBioaccumulationMobility
titanium dioxideHIGHLOWHIGH
2,2,4-trimethyl-1,3-pentanediol monoisobutyrateLOWLOWHIGH
waterLOWLOWHIGH

 

Section 13 - DISPOSAL CONSIDERATIONS

· Recycle wherever possible.
· Consult manufacturer for recycling options or consult local or regional waste management authority for disposal if no suitable treatment or disposal facility can be identified.
· Dispose of by: burial in a land-fill specifically licenced to accept chemical and / or pharmaceutical wastes or incineration in a licenced apparatus (after admixture with suitable combustible material).
· Decontaminate empty containers. Observe all label safeguards until containers are cleaned and destroyed.

Section 14 - TRANSPORTATION INFORMATION

HAZCHEM:

None (ADG7)
NOT REGULATED FOR TRANSPORT OF DANGEROUS GOODS: ADG7, UN, IATA, IMDG

Section 15 - REGULATORY INFORMATION

POISONS SCHEDULE

None

REGULATIONS

Regulations for ingredients

calcium carbonate (CAS: 471-34-1,13397-26-7,15634-14-7,1317-65-3) is found on the following regulatory lists;

"Australia High Volume Industrial Chemical List (HVICL)","Australia Inventory of Chemical Substances (AICS)","Australia Therapeutic Goods Administration (TGA) Substances that may be used as active ingredients in Listed medicines","CODEX General Standard for Food Additives (GSFA) - Additives Permitted for Use in Food in General, Unless Otherwise Specified, in Accordance with GMP","GESAMP/EHS Composite List - GESAMP Hazard Profiles","IMO IBC Code Chapter 17: Summary of minimum requirements","International Council of Chemical Associations (ICCA) - High Production Volume List","OECD Representative List of High Production Volume (HPV) Chemicals"

titanium dioxide (CAS: 13463-67-7,1317-70-0,1317-80-2,12188-41-9,1309-63-3,100292-32-8,101239-53-6,116788-85-3,12000-59-8,12701-76-7,12767-65-6,12789-63-8,1344-29-2,185323-71-1,185828-91-5,188357-76-8,188357-79-1,195740-11-5,221548-98-7,224963-00-2,246178-32-5,252962-41-7,37230-92-5,37230-94-7,37230-95-8,37230-96-9,39320-58-6,39360-64-0,39379-02-7,416845-43-7,494848-07-6,494848-23-6,494851-77-3,494851-98-8,55068-84-3,55068-85-4,552316-51-5,62338-64-1,767341-00-4,97929-50-5,98084-96-9) is found on the following regulatory lists;

"Australia Exposure Standards","Australia High Volume Industrial Chemical List (HVICL)","Australia Inventory of Chemical Substances (AICS)","Australia Therapeutic Goods Administration (TGA) Substances that may be used as active ingredients in Listed medicines","Australia Therapeutic Goods Administration (TGA) Sunscreening agents permitted as active ingredients in listed products","CODEX General Standard for Food Additives (GSFA) - Additives Permitted for Use in Food in General, Unless Otherwise Specified, in Accordance with GMP","GESAMP/EHS Composite List - GESAMP Hazard Profiles","IMO IBC Code Chapter 17: Summary of minimum requirements","International Agency for Research on Cancer (IARC) - Agents Reviewed by the IARC Monographs","OECD Representative List of High Production Volume (HPV) Chemicals"

2,2,4-trimethyl-1,3-pentanediol monoisobutyrate (CAS: 25265-77-4,77-68-9) is found on the following regulatory lists;

"Australia High Volume Industrial Chemical List (HVICL)","Australia Inventory of Chemical Substances (AICS)","GESAMP/EHS Composite List - GESAMP Hazard Profiles","IMO IBC Code Chapter 17: Summary of minimum requirements","IMO MARPOL 73/78 (Annex II) - List of Noxious Liquid Substances Carried in Bulk","OECD Representative List of High Production Volume (HPV) Chemicals"

water (CAS: 7732-18-5) is found on the following regulatory lists;

"Australia Inventory of Chemical Substances (AICS)","IMO IBC Code Chapter 18: List of products to which the Code does not apply","OECD Representative List of High Production Volume (HPV) Chemicals"

No data for Solver 4595 Maxi Ceiling Paint (CW: 5131-58)

No data for acrylic polymer latex (CAS: , Not avail)

Section 16 - OTHER INFORMATION

Denmark Advisory list for selfclassification of dangerous substances

Substance CAS Suggested codes
2, 2, 4- trimethyl- 1, 3- pentanediol 25265- 77- 4 N R50
monoisobutyrate
2, 2, 4- trimethyl- 1, 3- pentanediol 77- 68- 9 N R50
monoisobutyrate

 

INGREDIENTS WITH MULTIPLE CAS NUMBERS

Ingredient Name CAS
calcium carbonate 471-34-1, 13397-26-7, 15634-14-7, 1317-65-3
titanium dioxide 13463-67-7, 1317-70-0, 1317-80-2, 12188-41-9, 1309-63-3, 100292-32-8, 101239-53-6, 116788-85-3, 12000-59-8, 12701-76-7, 12767-65-6, 12789-63-8, 1344-29-2, 185323-71-1, 185828-91-5, 188357-76-8, 188357-79-1, 195740-11-5, 221548-98-7, 224963-00-2, 246178-32-5, 252962-41-7, 37230-92-5, 37230-94-7, 37230-95-8, 37230-96-9, 39320-58-6, 39360-64-0, 39379-02-7, 416845-43-7, 494848-07-6, 494848-23-6, 494851-77-3, 494851-98-8, 55068-84-3, 55068-85-4, 552316-51-5, 62338-64-1, 767341-00-4, 97929-50-5, 98084-96-9
2,2,4-trimethyl-1,3-pentanediol monoisobutyrate 25265-77-4, 77-68-9

 

■ Classification of the preparation and its individual components has drawn on official and authoritative sources as well as independent review by the Chemwatch Classification committee using available literature references.
A list of reference resources used to assist the committee may be found at:
www.chemwatch.net/references.

 

■ The (M)SDS is a Hazard Communication tool and should be used to assist in the Risk Assessment. Many factors determine whether the reported Hazards are Risks in the workplace or other settings.

 

This document is copyright. Apart from any fair dealing for the purposes of private study, research, review or
criticism, as permitted under the Copyright Act, no part may be reproduced by any process without written
permission from CHEMWATCH. TEL (+61 3) 9572 4700.

 

Issue Date: 2-Jul-2008

Print Date: 24-Aug-2010

 

 

This is the end of the MSDS.