SOLVER 4171 HIGH GLOSS ENAMEL ULTRA TINT BASE
Chemwatch Independent Material Safety Data Sheet
Issue Date: 19-Feb-2008
C9317EC
CHEMWATCH 5091-46
Version No:3
SOLVER 4171 HIGH GLOSS ENAMEL ULTRA TINT BASE
PAINT
None
High gloss enamel tinting base.
• Used according to manufacturer's directions.
The use of a quantity of material in an unventilated or confined space may result in increased exposure and an irritating atmosphere developing. Before starting consider control of exposure by mechanical ventilation.
Company: Solver Paints Pty Ltd
Address:
560 Churchill Road
Kilburn
SA, 5084
Australia
Telephone: +61 8 8368 1200
Emergency Tel: 1800 039 008 (24 hours)
Emergency Tel: +61 3 9573 3112
Fax: +61 8 8368 1222
HAZARDOUS SUBSTANCE. DANGEROUS GOODS. According to NOHSC Criteria, and ADG Code.
None
Risk Codes Risk Phrases
R10 • Flammable.
R38 • Irritating to skin.
R52/53 • Harmful to aquatic organisms may cause long- term adverse
effects in the aquatic environment.
R63(3) • Possible risk of harm to the unborn child.
R65 • HARMFUL- May cause lung damage if swallowed.
Safety Codes Safety Phrases
S36 • Wear suitable protective clothing.
S401 • To clean the floor and all objects contaminated by this
material use water and detergent.
S13 • Keep away from food drink and animal feeding stuffs.
S46 • If swallowed IMMEDIATELY contact Doctor or Poisons
Information Centre. (show this container or label).
S60 • This material and its container must be disposed of as
hazardous waste.
| NAME | CAS RN | % |
| alkyd resin - unregulated | 63148-69-6 | >60 |
| white spirit | 8052-41-3. | 5-15 |
| turpentine substitute | 8030-30-6. | 1-9 |
| titanium dioxide | 13463-67-7 | 1-5 |
| additives | 1-9 |
· Immediately give a glass of water.
· First aid is not generally required. If in doubt, contact a Poisons Information Centre or a doctor.
• If this product comes in contact with eyes:
· Wash out immediately with water.
· If irritation continues, seek medical attention.
· Removal of contact lenses after an eye injury should only be undertaken by skilled personnel.
• If skin or hair contact occurs:
· Flush skin and hair with running water (and soap if available).
· Seek medical attention in event of irritation.
· If fumes or combustion products are inhaled remove from contaminated area.
· Other measures are usually unnecessary.
• Treat symptomatically. Any material aspirated during vomiting may produce lung injury. Therefore emesis should not be induced mechanically or pharmacologically. For acute or short term repeated exposures to petroleum distillates or related hydrocarbons: · Primary threat to life, from pure petroleum distillate ingestion and/or inhalation, is respiratory failure. · Patients should be quickly evaluated for signs of respiratory distress (e.g. cyanosis, tachypnoea, intercostal retraction, obtundation) and given oxygen. Patients with inadequate tidal volumes or poor arterial blood gases (pO2 50 mm Hg) should be intubated. · Arrhythmias complicate some hydrocarbon ingestion and/or inhalation and electrocardiographic evidence of myocardial injury has been reported; intravenous lines and cardiac monitors should be established in obviously symptomatic patients. The lungs excrete inhaled solvents, so that hyperventilation improves clearance. · A chest x-ray should be taken immediately after stabilisation of breathing and circulation to document aspiration and detect the presence of pneumothorax.
· Foam. · Dry chemical powder. · BCF (where regulations permit). · Carbon dioxide.
· Alert Fire Brigade and tell them location and nature of hazard. · May be violently or explosively reactive. · Wear breathing apparatus plus protective gloves. · Prevent, by any means available, spillage from entering drains or water course. When any large container (including road and rail tankers) is involved in a fire, consider evacuation by 500 metres in all directions.
· Liquid and vapour are flammable. · Moderate fire hazard when exposed to heat or flame. · Vapour forms an explosive mixture with air. · Moderate explosion hazard when exposed to heat or flame. Combustion products include: carbon dioxide (CO2), other pyrolysis products typical of burning organic material.
· Avoid contamination with oxidising agents i.e. nitrates, oxidising acids, chlorine bleaches, pool chlorine etc. as ignition may result.
•3Y
| Glasses: | Gloves: | Respirator: |
| Chemical goggles. | PVC chemical resistant type. | Type A-P Filter of sufficient capacity |
· Remove all ignition sources. · Clean up all spills immediately. · Avoid breathing vapours and contact with skin and eyes. · Control personal contact by using protective equipment.
· Clear area of personnel and move upwind. · Alert Fire Brigade and tell them location and nature of hazard. · May be violently or explosively reactive. · Wear breathing apparatus plus protective gloves.
Personal Protective Equipment advice is contained in Section 8 of the MSDS.
· Avoid all personal contact, including inhalation.
· Wear protective clothing when risk of overexposure occurs.
· Use in a well-ventilated area.
· Prevent concentration in hollows and sumps.
· Packing as supplied by manufacturer.
· Plastic containers may only be used if approved for flammable liquid.
· Check that containers are clearly labelled and free from leaks.
· Avoid reaction with oxidising agents.
· Store in original containers in approved flammable liquid storage area.
· Store away from incompatible materials in a cool, dry, well-ventilated area.
· DO NOT store in pits, depressions, basements or areas where vapours may be trapped.
· No smoking, naked lights, heat or ignition sources.
| Source | Material | TWA mg/m³ | Notes |
| ___________ | ___________ | _______ | _______ |
| Australia Exposure Standards | white spirit (White spirits) | 790 | (see Chapter 16) |
| Australia Exposure Standards | white spirit (Petrol (gasoline)) | 900 | (see Chapter 16) |
| Australia Exposure Standards | turpentine substitute (Petrol (gasoline)) | 900 | (see Chapter 16) |
| Australia Exposure Standards | titanium dioxide (Titanium dioxide (a)) | 10 | (see Chapter 14) |
The following materials had no OELs on our records
| • alkyd resin - unregulated: | CAS:63148-69-6 |
Type A-P Filter of sufficient capacity
· Safety glasses with side shields · Chemical goggles. · Contact lenses may pose a special hazard; soft contact lenses may absorb and concentrate irritants. A written policy document, describing the wearing of lens or restrictions on use, should be created for each workplace or task. This should include a review of lens absorption and adsorption for the class of chemicals in use and an account of injury experience. Medical and first-aid personnel should be trained in their removal and suitable equipment should be readily available. In the event of chemical exposure, begin eye irrigation immediately and remove contact lens as soon as practicable. Lens should be removed at the first signs of eye redness or irritation - lens should be removed in a clean environment only after workers have washed hands thoroughly. [CDC NIOSH Current Intelligence Bulletin 59].
· Wear chemical protective gloves, eg. PVC. · Wear safety footwear or safety gumboots, eg. Rubber.
· Overalls. · PVC Apron. · PVC protective suit may be required if exposure severe. · Eyewash unit.
• For flammable liquids and flammable gases, local exhaust ventilation or a process enclosure ventilation system may be required. Ventilation equipment should be explosion-resistant. Air contaminants generated in the workplace possess varying "escape" velocities which, in turn, determine the "capture velocities" of fresh circulating air required to effectively remove the contaminant.
| Type of Contaminant: | Air Speed: |
| solvent, vapours, degreasing etc., evaporating from tank (in still air). | 0.25-0.5 m/s (50-100 f/min.) |
| aerosols, fumes from pouring operations, intermittent container filling, low speed conveyer transfers, welding, spray drift, plating acid fumes, pickling (released at low velocity into zone of active generation) | 0.5-1 m/s (100-200 f/min.) |
| direct spray, spray painting in shallow booths, drum filling, conveyer loading, crusher dusts, gas discharge (active generation into zone of rapid air motion) | 1-2.5 m/s (200-500 f/min.) |
White flammable liquid with a solvent odout; does not mix with water.
Liquid.
Does not mix with water.
Floats on water.
| State | Liquid | Molecular Weight | Not Available |
| Melting Range (ºC) | Not Available | Viscosity | Not Available |
| Boiling Range (ºC) | Not Available | Solubility in water (g/L) | Immiscible |
| Flash Point (ºC) | 31-36 | pH (1% solution) | Not Available |
| Decomposition Temp (ºC) | Not Available | pH (as supplied) | Not Available |
| Autoignition Temp (ºC) | Not Available | Vapour Pressure (kPa) | Not Available |
| Upper Explosive Limit (%) | Not Available | Specific Gravity (water=1) | 0.92-0.96 |
| Lower Explosive Limit (%) | Not Available | Relative Vapour Density (air=1) | >1 |
| Volatile Component (%vol) | Not Available | Evaporation Rate | Not Available |
· Presence of incompatible materials.
· Product is considered stable.
· Hazardous polymerisation will not occur.
For incompatible materials - refer to Section 7 - Handling and Storage.
| ACUTE HEALTH EFFECTS | CHRONIC HEALTH EFFECTS |
| • Irritating to skin. | • Possible risk of harm to the unborn child. |
| • HARMFUL-May cause lung damage if swallowed. | |
| • Vapours may cause dizziness or suffocation. |
TURPENTINE SUBSTITUTE: TITANIUM DIOXIDE: WHITE SPIRIT: • unless otherwise specified data extracted from RTECS - Register of Toxic Effects of Chemical Substances. TURPENTINE SUBSTITUTE: WHITE SPIRIT: • for petroleum: This product contains benzene which is known to cause acute myeloid leukaemia and n-hexane which has been shown to metabolize to compounds which are neuropathic. This product contains toluene. This product contains ethyl benzene and naphthalene from which there is evidence of tumours in rodents Carcinogenicity: Inhalation exposure to mice causes liver tumours, which are not considered relevant to humans. • None assigned. Refer to individual constituents. ALKYD RESIN - UNREGULATED: • "alkyd resin" describes a generic insoluble polymer which has no residual hazardous reactants and is not absorbed in the gastro-intestinal tract. No acute or chronic human exposure / toxicity data available. WHITE SPIRIT:
| TOXICITY | IRRITATION |
| Inhalation (human) TCLo: 600 mg/m³/8h | Nil Reported |
| Oral (rat) LD50: >5000 mg/kg | Eye (human): 470 ppm/15m |
| Inhalation (rat) LC50: >5500 mg/m³/4h | Eye (rabbit): 500 mg/24h Moderate |
| TOXICITY | IRRITATION |
| Oral (Rat) LD50: >20000 mg/kg * | Skin (human): 0.3 mg /3D (int)-Mild * |
| Oral (Mouse) LD50: >10000 mg/kg * |
| Gasoline (NB: Overall evaluation upgraded from 3 to 2B with supporting evidence from other relevant data) | International Agency for Research on Cancer (IARC) - Agents Reviewed by the IARC Monographs | Group | 2B |
| Crude oil | International Agency for Research on Cancer (IARC) - Agents Reviewed by the IARC Monographs | Group | 3 |
| Titanium dioxide | International Agency for Research on Cancer (IARC) - Agents Reviewed by the IARC Monographs | Group | 2B |
Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment. This material and its container must be disposed of as hazardous waste.
| Ingredient | Persistence: Water/Soil | Persistence: Air | Bioaccumulation | Mobility |
| titanium dioxide | HIGH | LOW | HIGH |
· Consult manufacturer for recycling options and recycle where possible .
· Consult State Land Waste Management Authority for disposal.
· Incinerate residue at an approved site.
· Recycle containers if possible, or dispose of in an authorised landfill.
Labels Required: FLAMMABLE LIQUID
•3Y (ADG7)
| Class or division: | 3 | Subsidiary risk: | None |
| UN No.: | 1263 | UN packing group: | III |
| Special provisions: | 163; 223 | Packing Instructions: | None |
| Limited quantities: | 5 L | Portable tanks and bulk containers - Instructions: | T2 |
| Portable tanks and bulk containers - Special provisions: | TP1; TP29 | Packagings and IBCs - Packing instruction: | P001; IBC03; LP01 |
| Packagings and IBCs - Special packing provisions: | PP1 |
| Class or division: | 3 | Subsidiary risk: | None |
| UN No.: | 1263 | UN packing group: | III |
| ICAO/IATA Class: | 3 | ICAO/IATA Subrisk: | None |
| UN/ID Number: | 1263 | Packing Group: | III |
| Special provisions: | A3 | ||
| IMDG Class: | 3 | IMDG Subrisk: | None |
| UN Number: | 1263 | Packing Group: | III |
| EMS Number: | F-E , S-E | Special provisions: | 163 223 955 |
| Limited Quantities: | 5 L |
None
Regulations for ingredients
"Australia Inventory of Chemical Substances (AICS)"
"Australia Exposure Standards","Australia Hazardous Substances","Australia Inventory of Chemical Substances (AICS)","Australia Standard for the Uniform Scheduling of Drugs and Poisons (SUSDP) - Appendix E (Part 2)","GESAMP/EHS Composite List - GESAMP Hazard Profiles","IMO IBC Code Chapter 17: Summary of minimum requirements","IMO Provisional Categorization of Liquid Substances - List 2: Pollutant only mixtures containing at least 99% by weight of components already assessed by IMO","International Council of Chemical Associations (ICCA) - High Production Volume List","OECD Representative List of High Production Volume (HPV) Chemicals"
"Australia Hazardous Substances","Australia Inventory of Chemical Substances (AICS)","GESAMP/EHS Composite List - GESAMP Hazard Profiles","IMO IBC Code Chapter 17: Summary of minimum requirements","IMO MARPOL 73/78 (Annex II) - List of Noxious Liquid Substances Carried in Bulk","IMO Provisional Categorization of Liquid Substances - List 2: Pollutant only mixtures containing at least 99% by weight of components already assessed by IMO","OECD Representative List of High Production Volume (HPV) Chemicals"
"Australia Exposure Standards","Australia High Volume Industrial Chemical List (HVICL)","Australia Inventory of Chemical Substances (AICS)","Australia Therapeutic Goods Administration (TGA) Substances that may be used as active ingredients in Listed medicines","Australia Therapeutic Goods Administration (TGA) Sunscreening agents permitted as active ingredients in listed products","CODEX General Standard for Food Additives (GSFA) - Additives Permitted for Use in Food in General, Unless Otherwise Specified, in Accordance with GMP","GESAMP/EHS Composite List - GESAMP Hazard Profiles","IMO IBC Code Chapter 17: Summary of minimum requirements","International Agency for Research on Cancer (IARC) - Agents Reviewed by the IARC Monographs","OECD Representative List of High Production Volume (HPV) Chemicals"
| Ingredient Name | CAS |
| white spirit | 8052-41-3, 8042-47-5 |
| titanium dioxide | 13463-67-7, 1317-70-0, 1317-80-2, 12188-41-9, 1309-63-3, 100292-32-8, 101239-53-6, 116788-85-3, 12000-59-8, 12701-76-7, 12767-65-6, 12789-63-8, 1344-29-2, 185323-71-1, 185828-91-5, 188357-76-8, 188357-79-1, 195740-11-5, 221548-98-7, 224963-00-2, 246178-32-5, 252962-41-7, 37230-92-5, 37230-94-7, 37230-95-8, 37230-96-9, 39320-58-6, 39360-64-0, 39379-02-7, 416845-43-7, 494848-07-6, 494848-23-6, 494851-77-3, 494851-98-8, 55068-84-3, 55068-85-4, 552316-51-5, 62338-64-1, 767341-00-4, 97929-50-5, 98084-96-9 |
• Classification of the preparation and its individual components has drawn on official and authoritative sources as well as independent review by the Chemwatch Classification committee using available literature references.
A list of reference resources used to assist the committee may be found at:
www.chemwatch.net/references.
• The (M)SDS is a Hazard Communication tool and should be used to assist in the Risk Assessment. Many factors determine whether the reported Hazards are Risks in the workplace or other settings.
This document is copyright. Apart from any fair dealing for the purposes of private study, research, review or
criticism, as permitted under the Copyright Act, no part may be reproduced by any process without written
permission from CHEMWATCH. TEL (+61 3) 9572 4700.
Issue Date: 19-Feb-2008
Print Date: 6-Aug-2010
This is the end of the MSDS.