SOLVER 4120 ZINC PHOSPHATE ANTI-CORROSIVE METAL PRIMER
Chemwatch Material Safety Data Sheet (REVIEW)
Issue Date: 7-Jul-2006
NC317TCP
CHEMWATCH 4603-96
Version No:3
SOLVER 4120 ZINC PHOSPHATE ANTI-CORROSIVE METAL PRIMER
"Anticorrosive Structural Primer Lead and Chromate free"
PAINT
Apply by brush, hand roller or spray atomisation. An industrial / architectural coating
for use on cleaned structural steel and clean non ferrous metals.
Company: Solver Paints Pty Ltd Company: Solver Paints Pty Ltd
Address: Address:
211 Collier Rd 560 Churchill Road
Bayswater Kilburn
WA, 6053 SA, 5084
AUS AUS
Telephone: +61 8 9449 8811 Telephone: +61 8 8368 1200
Fax: +61 8 9371 5872 Emergency Tel: 1800 039 008 (24 hours)
Emergency Tel: +61 3 9573 3112
Fax: +61 8 8368 1222
| Flammability | 2 | |
| Toxicity | 2 | |
| Body Contact | 2 | |
| Reactivity | 1 | |
| Chronic | 2 | |
| SCALE: Min/Nil=0 Low=1 Moderate=2 High=3 Extreme=4 | ||
HAZARDOUS SUBSTANCE. DANGEROUS GOODS. According to the Criteria of NOHSC,
and the ADG Code.
S5
| RISK | SAFETY |
| Flammable. | Keep away from sources of ignition. No smoking. |
| Irritating to eyes, respiratory system and skin. | Keep container in a well ventilated place. |
| Limited evidence of a carcinogenic effect. | Avoid exposure - obtain special instructions before use. |
| Harmful: danger of serious damage to health by prolonged exposure through inhalation. | To clean the floor and all objects contaminated by this material, use water and detergent. |
| Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. | Keep container tightly closed. |
| Possible risk of harm to the unborn child. | This material and its container must be disposed of in a safe way. |
| HARMFUL-May cause lung damage if swallowed. | Keep away from food, drink and animal feeding stuffs. |
| Vapours may cause drowsiness and dizziness. | Take off immediately all contaminated clothing. |
| Inhalation and/or ingestion may produce health damage*. | In case of contact with eyes, rinse with plenty of water and contact Doctor or Poisons Information Centre. |
| Cumulative effects may result following exposure*. | If swallowed, IMMEDIATELY contact Doctor or Poisons Information Centre. (show this container or label). |
| * (limited evidence). | Use appropriate container to avoid environment contamination. |
| Avoid release to the environment. Refer to special instructions/Safety data sheets. | |
| This material and its container must be disposed of as hazardous waste. |
| NAME | CAS RN | % |
| alkyd resin solution | Various | 30-60 |
| mineral turpentine | Not avail. | 1-20 |
| zinc phosphate | 7779-90-0 | 1-10 |
| aromatic solvent 100 | Not avail. | <5 |
| pigment unregulated | 10-30 | |
| some colours may contain | ||
| titanium dioxide | 13463-67-7 | |
| additives | 1-10 | |
| NOTE: Manufacturer has supplied full ingredient | ||
| information to allow CHEMWATCH assessment. |
If spontaneous vomiting appears imminent or occurs, hold patient's head down, lower than
their hips to help avoid possible aspiration of vomitus.
· If swallowed do NOT induce vomiting.
· If vomiting occurs, lean patient forward or place on left side (head-down position, if
possible) to maintain open airway and prevent aspiration.
· Observe the patient carefully.
· Never give liquid to a person showing signs of being sleepy or with reduced awareness;
i.e. becoming unconscious.
· Give water to rinse out mouth, then provide liquid slowly and as much as casualty can
comfortably drink.
· Seek medical advice.
Avoid giving milk or oils.
Avoid giving alcohol.
If this product comes in contact with the eyes:
· Wash out immediately with fresh running water.
· Ensure complete irrigation of the eye by keeping eyelids apart and away from eye and
moving the eyelids by occasionally lifting the upper and lower lids.
· If pain persists or recurs seek medical attention.
· Removal of contact lenses after an eye injury should only be undertaken by skilled
personnel.
If skin contact occurs:
· Immediately remove all contaminated clothing, including footwear.
· Flush skin and hair with running water (and soap if available).
· Seek medical attention in event of irritation.
· If fumes or combustion products are inhaled remove from contaminated area.
· Lay patient down. Keep warm and rested.
· Prostheses such as false teeth, which may block airway, should be removed, where
possible, prior to initiating first aid procedures.
· Apply artificial respiration if not breathing, preferably with a demand valve
resuscitator, bag-valve mask device, or pocket mask as trained. Perform CPR if necessary.
· Transport to hospital, or doctor.
Any material aspirated during vomiting may produce lung injury. Therefore emesis should not be induced mechanically or pharmacologically. Mechanical means should be used if it is considered necessary to evacuate the stomach contents; these include gastric lavage after endotracheal intubation. If spontaneous vomiting has occurred after ingestion, the patient should be monitored for difficult breathing, as adverse effects of aspiration into the lungs may be delayed up to 48 hours. For acute or short term repeated exposures to petroleum distillates or related hydrocarbons: · Primary threat to life, from pure petroleum distillate ingestion and/or inhalation, is respiratory failure. · Patients should be quickly evaluated for signs of respiratory distress (e.g. cyanosis, tachypnoea, intercostal retraction, obtundation) and given oxygen. Patients with inadequate tidal volumes or poor arterial blood gases (pO2 50 mm Hg) should be intubated. · Arrhythmias complicate some hydrocarbon ingestion and/or inhalation and electrocardiographic evidence of myocardial injury has been reported; intravenous lines and cardiac monitors should be established in obviously symptomatic patients. The lungs excrete inhaled solvents, so that hyperventilation improves clearance. · A chest x-ray should be taken immediately after stabilisation of breathing and circulation to document aspiration and detect the presence of pneumothorax. · Epinephrine (adrenalin) is not recommended for treatment of bronchospasm because of potential myocardial sensitisation to catecholamines. Inhaled cardioselective bronchodilators (e.g. Alupent, Salbutamol) are the preferred agents, with aminophylline a second choice. · Lavage is indicated in patients who require decontamination; ensure use of cuffed endotracheal tube in adult patients. [Ellenhorn and Barceloux: Medical Toxicology].
· Foam.
· Dry chemical powder.
· BCF (where regulations permit).
· Carbon dioxide.
· Water spray or fog - Large fires only.
· Alert Fire Brigade and tell them location and nature of hazard.
· May be violently or explosively reactive.
· Wear breathing apparatus plus protective gloves.
· Prevent, by any means available, spillage from entering drains or water course.
· If safe, switch off electrical equipment until vapour fire hazard removed.
· Use water delivered as a fine spray to control fire and cool adjacent area.
· Avoid spraying water onto liquid pools.
· DO NOT approach containers suspected to be hot.
· Cool fire exposed containers with water spray from a protected location.
· If safe to do so, remove containers from path of fire.
· Liquid and vapour are flammable.
· Moderate fire hazard when exposed to heat or flame.
· Vapour forms an explosive mixture with air.
· Moderate explosion hazard when exposed to heat or flame.
· Vapour may travel a considerable distance to source of ignition.
· Heating may cause expansion or decomposition leading to violent rupture of containers.
· On combustion, may emit toxic fumes of carbon monoxide (CO).
Combustion products include: carbon monoxide (CO), carbon dioxide (CO2), other
pyrolysis products typical of burning organic material.
Avoid contamination with oxidising agents i.e. nitrates, oxidising acids, chlorine
bleaches, pool chlorine etc. as ignition may result.
Gloves, boots (chemical resistant).
Breathing apparatus.
· Remove all ignition sources. · Clean up all spills immediately. · Avoid breathing vapours and contact with skin and eyes. · Control personal contact by using protective equipment. · Contain and absorb small quantities with vermiculite or other absorbent material. · Wipe up. · Collect residues in a flammable waste container.
· Clear area of personnel and move upwind. · Alert Fire Brigade and tell them location and nature of hazard. · May be violently or explosively reactive. · Wear breathing apparatus plus protective gloves. · Prevent, by any means available, spillage from entering drains or water course. · No smoking, naked lights or ignition sources. · Increase ventilation. · Stop leak if safe to do so. · Water spray or fog may be used to disperse / absorb vapour. · Contain spill with sand, earth or vermiculite. · Use only spark-free shovels and explosion proof equipment. · Collect recoverable product into labelled containers for recycling. · Absorb remaining product with sand, earth or vermiculite. · Collect solid residues and seal in labelled drums for disposal. · Wash area and prevent runoff into drains. · If contamination of drains or waterways occurs, advise emergency services.
From IERG (Canada/Australia) Isolation Distance 25 metres Downwind Protection Distance 300 metres IERG Number 14
FOOTNOTES
1 PROTECTIVE ACTION ZONE is defined as the area in which people are at risk of harmful exposure. This zone
assumes that random changes in wind direction confines the vapour plume to an area within 30 degrees on
either side of the predominant wind direction, resulting in a crosswind protective action distance equal
to the downwind protective action distance.
2 PROTECTIVE ACTIONS should be initiated to the extent possible, beginning with those closest to the spill
and working away from the site in the downwind direction. Within the protective action zone a level of
vapour concentration may exist resulting in nearly all unprotected persons becoming incapacitated and
unable to take protective action and/or incurring serious or irreversible health effects.
3 INITIAL ISOLATION ZONE is determined as an area, including upwind of the incident, within which a high
probability of localised wind reversal may expose nearly all persons without appropriate protection to
life-threatening concentrations of the material.
4 SMALL SPILLS involve a leaking package of 200 litres (55 US gallons) or less, such as a drum (jerrican or
box with inner containers). Larger packages leaking less than 200 litres and compressed gas leaking from
a small cylinder are also considered "small spills".
LARGE SPILLS involve many small leaking packages or a leaking package of greater than 200 litres, such as
a cargo tank, portable tank or a "one-tonne" compressed gas cylinder.
5 Guide 128 is taken from the US DOT emergency response guide book.
6 IERG information is derived from CANUTEC - Transport Canada.
The maximum airborne concentration below which it is believed that nearly all individuals could be exposed
for up to one hour WITHOUT experiencing or developing
life-threatening health effects is:
zinc phosphate 250 mg/m³
irreversible or other serious effects or symptoms which could impair an individual's ability to take
protective action is:
zinc phosphate 50 mg/m³
other than mild, transient adverse effects without perceiving a clearly defined odour is:
zinc phosphate 6 mg/m³
The threshold concentration below which most people will experience no appreciable risk of health effects:
zinc phosphate 2 mg/m³
American Industrial Hygiene Association (AIHA)
Ingredients considered according to the following cutoffs
Very Toxic (T+) >= 0.1% Toxic (T) >= 3.0%
R50 >= 0.25% Corrosive (C) >= 5.0%
R51 >= 2.5%
else >= 10%
where percentage is percentage of ingredient found in the mixture
___________________________________________
| + | X | X | X | X | + |
___________________________________________
+: May be stored together
O: May be stored together with specific preventions
X: Must not be stored together
Personal Protective Equipment advice is contained in Section 8 of the MSDS.
· Containers, even those that have been emptied, may contain explosive vapours.
· Do NOT cut, drill, grind, weld or perform similar operations on or near containers.
· Avoid all personal contact, including inhalation.
· Wear protective clothing when risk of overexposure occurs.
· Use in a well-ventilated area.
· Prevent concentration in hollows and sumps.
· DO NOT enter confined spaces until atmosphere has been checked.
· Avoid smoking, naked lights or ignition sources.
· Avoid generation of static electricity.
· DO NOT use plastic buckets.
· Earth all lines and equipment.
· Use spark-free tools when handling.
· Avoid contact with incompatible materials.
· When handling, DO NOT eat, drink or smoke.
· Keep containers securely sealed when not in use.
· Avoid physical damage to containers.
· Always wash hands with soap and water after handling.
· Work clothes should be laundered separately.
· Use good occupational work practice.
· Observe manufacturer's storing and handling recommendations.
· Atmosphere should be regularly checked against established exposure standards to ensure
safe working conditions.
DO NOT allow clothing wet with material to stay in contact with skin.
Packing as supplied by manufacturer. Plastic containers may only be used if approved for
flammable liquid. Check that containers are clearly labelled and free from leaks.
· For low viscosity materials (i) : Drums and jerry cans must be of the non-removable
head type. (ii) : Where a can is to be used as an inner package, the can must have a
screwed enclosure.
· For materials with a viscosity of at least 2680 cSt. (23 deg. C)
· For manufactured product having a viscosity of at least 250 cSt. (23 deg. C)
· Manufactured product that requires stirring before use and having a viscosity of at
least 20 cSt (25 deg. C)
(i) : Removable head packaging;
(ii) : Cans with friction closures and
(iii) : low pressure tubes and cartridges may be used.
· Where combination packages are used, and the inner packages are of glass, there must be
sufficient inert cushioning material in contact with inner and outer packages
· In addition, where inner packagings are glass and contain liquids of packing group I
there must be sufficient inert absorbent to absorb any spillage, unless the outer
packaging is a close fitting moulded plastic box and the substances are not incompatible
with the plastic.
· Phosphates are incompatible with oxidising and reducing agents.
· Phosphates are susceptible to formation of highly toxic and flammable phosphine gas in
the presence of strong reducing agents such as hydrides.
· Partial oxidation of phosphates by oxidizing agents may result in the release of toxic
phosphorus oxides.
Avoid reaction with oxidising agents.
· Store in original containers in approved flammable liquid storage area.
· DO NOT store in pits, depressions, basements or areas where vapours may be trapped.
· No smoking, naked lights, heat or ignition sources.
· Keep containers securely sealed.
· Store away from incompatible materials in a cool, dry, well-ventilated area.
· Protect containers against physical damage and check regularly for leaks.
· Observe manufacturer's storing and handling recommendations.
Source Material TWA TWA STEL STEL Peak Peak TWA
ppm mg/m³ ppm mg/m³ ppm mg/m³ F/CC
_________________ __________________ _____ _____ _____ _____ _____ _____ _____
Source Material TWA TWA STEL STEL Peak Peak TWA
ppm mg/m³ ppm mg/m³ ppm mg/m³ F/CC
_________________ __________________ _____ _____ _____ _____ _____ _____ _____
Australia Exposure zinc phosphate 10
Standards (Inspirable dust
(Not specified))
Australia Exposure titanium dioxide 10
Standards (Titanium dioxide
(a))
| Material | Revised IDLH Value (mg/m3) | Revised IDLH Value (ppm) |
| titanium dioxide | 5,000 |
OSF=0.042 (mineral turpentine) Exposed individuals are NOT reasonably expected to be warned, by smell, that the Exposure Standard is being exceeded. Odour Safety Factor (OSF) is determined to fall into either Class C, D or E. The Odour Safety Factor (OSF) is defined as: OSF= Exposure Standard (TWA) ppm/ Odour Threshold Value (OTV) ppm Classification into classes follows:
| Class | OSF | Description |
| A | 550 | Over 90% of exposed individuals are aware by smell that the Exposure Standard (TLV-TWA for example) is being reached, even when distracted by working activities |
| B | 26-550 | As "A" for 50-90% of persons being distracted |
| C | 1-26 | As "A" for less than 50% of persons being distracted |
| D | 0.18-1 | 10-50% of persons aware of being tested perceive by smell that the Exposure Standard is being reached |
| E | <0.18 | As "D" for less than 10% of persons aware of being tested |
None assigned. Refer to individual constituents.
ALKYD RESIN SOLUTION: No exposure limits set by NOHSC or ACGIH. MINERAL TURPENTINE: CEL TWA: 80 ppm, 480 mg/m3 [Shell] AROMATIC SOLVENT 100: CEL TWA: 50 ppm, 250 mg/m3 as total hydrocarbons [Manufacturer] TITANIUM DIOXIDE: It is the goal of the ACGIH (and other Agencies) to recommend TLVs (or their equivalent) for all substances for which there is evidence of health effects at airborne concentrations encountered in the workplace. At this time no TLV has been established, even though this material may produce adverse health effects (as evidenced in animal experiments or clinical experience). Airborne concentrations must be maintained as low as is practically possible and occupational exposure must be kept to a minimum. NOTE: The ACGIH occupational exposure standard for Particles Not Otherwise Specified (P.N.O.S) does NOT apply. Sensory irritants are chemicals that produce temporary and undesirable side-effects on the eyes, nose or throat. Historically occupational exposure standards for these irritants have been based on observation of workers' responses to various airborne concentrations. Present day expectations require that nearly every individual should be protected against even minor sensory irritation and exposure standards are established using uncertainty factors or safety factors of 5 to 10 or more. On occasion animal no -observable-effect-levels (NOEL) are used to determine these limits where human results are unavailable. An additional approach, typically used by the TLV committee (USA) in determining respiratory standards for this group of chemicals, has been to assign ceiling values (TLV C) to rapidly acting irritants and to assign short-term exposure limits (TLV STELs) when the weight of evidence from irritation, bioaccumulation and other endpoints combine to warrant such a limit. In contrast the MAK Commission (Germany) uses a five -category system based on intensive odour, local irritation, and elimination half-life. However this system is being replaced to be consistent with the European Union (EU) Scientific Committee for Occupational Exposure Limits (SCOEL); this is more closely allied to that of the USA. OSHA (USA) concluded that exposure to sensory irritants can: · cause inflammation · cause increased susceptibility to other irritants and infectious agents · lead to permanent injury or dysfunction · permit greater absorption of hazardous substances and · acclimate the worker to the irritant warning properties of these substances thus increasing the risk of overexposure. WARNING: This substance has been classified by the IARC as Group 2B: Possibly Carcinogenic to Humans. IDLH Level: 5000 mg/m3 Animal studies at 10 mg/m3 show no significant fibrosis, possibly reversible tissue reaction and the architecture of lung air spaces remains intact.
· Safety glasses with side shields. · Chemical goggles. · Contact lenses may pose a special hazard; soft contact lenses may absorb and concentrate irritants. A written policy document, describing the wearing of lens or restrictions on use, should be created for each workplace or task. This should include a review of lens absorption and adsorption for the class of chemicals in use and an account of injury experience. Medical and first-aid personnel should be trained in their removal and suitable equipment should be readily available. In the event of chemical exposure, begin eye irrigation immediately and remove contact lens as soon as practicable. Lens should be removed at the first signs of eye redness or irritation - lens should be removed in a clean environment only after workers have washed hands thoroughly. [CDC NIOSH Current Intelligence Bulletin 59].
Suitability and durability of glove type is dependent on usage. Factors such as: · frequency and duration of contact, · chemical resistance of glove material, · glove thickness and · dexterity, are important in the selection of gloves. Wear chemical protective gloves, eg. PVC. Wear safety footwear or safety gumboots, eg. Rubber.
· Overalls. · PVC Apron. · PVC protective suit may be required if exposure severe. · Eyewash unit. · Ensure there is ready access to a safety shower.
Respiratory protection may be required when ANY "Worst Case" vapour-phase concentration is exceeded (see Computer Prediction in "Exposure Standards").
| Protection Factor | Half-Face Respirator | Full-Face Respirator | |
| 10 x ES | A-AUS | - | |
| A-PAPR-AUS | |||
| 50 x ES | Air-line* | - | |
| 100 x ES | - | A-3 | |
| 100+ x ES | - | Air-line** | |
For flammable liquids and flammable gases, local exhaust ventilation or a process enclosure ventilation system may be required. Ventilation equipment should be explosion -resistant. Air contaminants generated in the workplace possess varying "escape" velocities which, in turn, determine the "capture velocities" of fresh circulating air required to effectively remove the contaminant.
| Type of Contaminant: | Air Speed: |
| solvent, vapours, degreasing etc., evaporating from tank (in still air). | 0.25-0.5 m/s (50-100 f/min.) |
| aerosols, fumes from pouring operations, intermittent container filling, low speed conveyer transfers, welding, spray drift, plating acid fumes, pickling (released at low velocity into zone of active generation) | 0.5-1 m/s (100-200 f/min.) |
| direct spray, spray painting in shallow booths, drum filling, conveyer loading, crusher dusts, gas discharge (active generation into zone of rapid air motion) | 1-2.5 m/s (200-500 f/min.) |
| Lower end of the range | Upper end of the range |
| 1: Room air currents minimal or favourable to capture | 1: Disturbing room air currents |
| 2: Contaminants of low toxicity or of nuisance value only. | 2: Contaminants of high toxicity |
| 3: Intermittent, low production. | 3: High production, heavy use |
| 4: Large hood or large air mass in motion | 4: Small hood-local control only |
Colours are lead and chromate pigment free. Coloured flammable liquid with a mild solvent odour; does not mix with water. Mixes with most organic solvents.
Liquid.
Does not mix with water.
Sinks in water.
| Molecular Weight: Not applicable | Boiling Range (�C): Not available |
| Melting Range (�C): Not available | Specific Gravity (water=1): 1.13-1.18 |
| Solubility in water (g/L): Immiscible | pH (as supplied): Not applicable |
| pH (1% solution): Not applicable | Vapour Pressure (kPa): Not available |
| Volatile Component (%vol): 45-55 | Evaporation Rate: Slow |
| Relative Vapour Density (air=1): >1 | Flash Point (�C): 36 |
| Lower Explosive Limit (%): Not available | Upper Explosive Limit (%): Not available |
| Autoignition Temp (�C): Not available | Decomposition Temp (�C): Not Available |
| State: Liquid | Viscosity: Not Available |
· Presence of incompatible materials.
· Product is considered stable.
· Hazardous polymerisation will not occur.
Accidental ingestion of the material may be damaging to the health of the individual. As absorption of phosphates from the bowel is poor, poisoning this way is less likely. Effects can include vomiting, tiredness, fever, diarrhoea, low blood pressure, slow pulse , cyanosis, spasms of the wrist, coma and severe body spasms. Considered an unlikely route of entry in commercial/industrial environments. The liquid may produce gastrointestinal discomfort and may be harmful if swallowed. Ingestion may result in nausea, pain and vomiting. Vomit entering the lungs by aspiration may cause potentially lethal chemical pneumonitis.
Although the liquid is not thought to be an irritant (as classified by EC Directives), direct contact with the eye may produce transient discomfort characterised by tearing or conjunctival redness (as with windburn).
This material can cause inflammation of the skin on contact in some persons. The material may accentuate any pre-existing dermatitis condition. Skin contact is not thought to have harmful health effects (as classified under EC Directives); the material may still produce health damage following entry through wounds, lesions or abrasions. Entry into the blood-stream, through, for example, cuts, abrasions or lesions, may produce systemic injury with harmful effects. Examine the skin prior to the use of the material and ensure that any external damage is suitably protected.
Inhalation of vapours or aerosols (mists, fumes), generated by the material during the course of normal handling, may be damaging to the health of the individual. There is some evidence to suggest that the material can cause respiratory irritation in some persons. The body's response to such irritation can cause further lung damage. Inhalation of high concentrations of gas/vapour causes lung irritation with coughing and nausea, central nervous depression with headache and dizziness, slowing of reflexes, fatigue and inco-ordination. Central nervous system (CNS) depression may include general discomfort, symptoms of giddiness, headache, dizziness, nausea, anaesthetic effects, slowed reaction time, slurred speech and may progress to unconsciousness. Serious poisonings may result in respiratory depression and may be fatal. If exposure to highly concentrated solvent atmosphere is prolonged this may lead to narcosis, unconsciousness, even coma and possible death.
There has been some concern that this material can cause cancer or mutations but there is not enough data to make an assessment. Substance accumulation, in the human body, may occur and may cause some concern following repeated or long-term occupational exposure. There is some evidence from animal testing that exposure to this material may result in toxic effects to the unborn baby. Chronic solvent inhalation exposures may result in nervous system impairment and liver and blood changes. [PATTYS]. Sodium phosphate dibasic can cause stones in the kidney, loss of mineral from the bones and loss of thyroid gland function.
Not available. Refer to individual constituents. ALKYD RESIN SOLUTION: "alkyd resin" describes a generic insoluble polymer which has no residual hazardous reactants and is not absorbed in the gastro-intestinal tract. No acute or chronic human exposure / toxicity data available. Almost always in solvent solution - the hazard is from the solvent. MINERAL TURPENTINE: Not available. Refer to individual constituents. ZINC PHOSPHATE: TOXICITY IRRITATION Oral (rat) LD50: 15000 mg/kg No data available [T [TAYC [TAYCA- Japan] AROMATIC SOLVENT 100: Not available. Refer to individual constituents. TITANIUM DIOXIDE: TOXICITY IRRITATION Skin (human): 0.3 mg/3d- I Mild The material may produce moderate eye irritation leading to inflammation. Repeated or prolonged exposure to irritants may produce conjunctivitis. The material may cause skin irritation after prolonged or repeated exposure and may produce on contact skin redness, swelling, the production of vesicles, scaling and thickening of the skin.
MATERIAL CARCINOGEN REPROTOXIN SENSITISER SKIN
________________________ ____________________ ________________ ________________ ________________
titanium dioxide IARC:2B
CARCINOGEN
IARC: International Agency for Research on Cancer (IARC) Carcinogens: titanium dioxide
Category: 2B
Marine Pollutant:Not Determined
Drinking Water Standards: hydrocarbon total: 10 ug/l (UK max.). The lower molecular weight hydrocarbons are expected to form a "slick" on the surface of waters after release in calm sea conditions. This is expected to evaporate and enter the atmosphere where it will be degraded through reaction with hydroxy radicals. Some of the material will become associated with benthic sediments, and it is likely to be spread over a fairly wide area of sea floor. Marine sediments may be either aerobic or anaerobic. The material, in probability, is biodegradable, under aerobic conditions (isomerised olefins and alkenes show variable results). Evidence also suggests that the hydrocarbons may be degradable under anaerobic conditions although such degradation in benthic sediments may be a relatively slow process. Under aerobic conditions the material will degrade to water and carbon dioxide, while under anaerobic processes it will produce water, methane and carbon dioxide. Based on test results, as well as theoretical considerations, the potential for bioaccumulation may be high. Toxic effects are often observed in species such as blue mussel, daphnia, freshwater green algae, marine copepods and amphipods. Do NOT allow product to come in contact with surface waters or to intertidal areas below the mean high water mark. Do not contaminate water when cleaning equipment or disposing of equipment wash-waters. Wastes resulting from use of the product must be disposed of on site or at approved waste sites. DO NOT discharge into sewer or waterways. Refer to data for ingredients, which follows: MINERAL TURPENTINE: DO NOT discharge into sewer or waterways. ZINC PHOSPHATE: The material is classified as an ecotoxin* because the Fish LC50 (96 hours) is less than or equal to 0.1 mg/l * Classification of Substances as Ecotoxic (Dangerous to the Environment) Appendix 8, Table 1 Compiler's Guide for the Preparation of International Chemical Safety Cards: 1993 Commission of the European Communities. TITANIUM DIOXIDE: DO NOT discharge into sewer or waterways.
· Recycle wherever possible.
· Consult manufacturer for recycling options or consult local or regional waste
management authority for disposal if no suitable treatment or disposal facility can be
identified.
· Dispose of by: Burial in a licenced land-fill or Incineration in a licenced apparatus
(after admixture with suitable combustible material).
· Decontaminate empty containers. Observe all label safeguards until containers are
cleaned and destroyed.
Labels Required: FLAMMABLE LIQUID HAZCHEM: 3[Y] UNDG:
| Dangerous Goods Class: | 3 | Subrisk: | None |
| UN Number: | 1263 | Packing Group: | III |
| ICAO/IATA Class: | 3 | ICAO/IATA Subrisk: | None |
| UN/ID Number: | 1263 | Packing Group: | III |
| ERG Code: | 3L |
| IMDG Class: | 3 | IMDG Subrisk: | None |
| UN Number: | 1263 | Packing Group: | III |
| EMS Number: | F-E,S-E | Marine Pollutant: | Not Determined |
alkyd resin solution (CAS No:Various): No regulations applicable zinc phosphate (CAS: 7779-90-0) is found on the following regulatory lists; Australia Exposure Standards Australia Inventory of Chemical Substances (AICS) Australia National Pollutant Inventory Australia Standard for the Uniform Scheduling of Drugs and Poisons (SUSDP) - Schedule 4 OECD Representative List of High Production Volume (HPV) Chemicals zinc phosphate (CAS: 7543-51-3) is found on the following regulatory lists; Australia Exposure Standards Australia National Pollutant Inventory Australia Standard for the Uniform Scheduling of Drugs and Poisons (SUSDP) - Schedule 4 titanium dioxide (CAS: 13463-67-7) is found on the following regulatory lists; Australia - Australia New Zealand Food Standards Code - Food Additives - Schedule 3 Colours permitted in accordance with GMP in processed foods specified in Schedule 1 Australia Exposure Standards Australia High Volume Industrial Chemical List (HVICL) Australia Inventory of Chemical Substances (AICS) Australia Therapeutic Goods Administration (TGA) Sunscreening agents permitted as active ingredients in listed products CODEX General Standard for Food Additives (GSFA) - Additives Permitted for Use in Food in General, Unless Otherwise Specified, in Accordance with GMP International Agency for Research on Cancer (IARC) Carcinogens OECD Representative List of High Production Volume (HPV) Chemicals No data available for alkyd resin solution as CAS: Various. No data available for mineral turpentine as CAS: Not avail. No data available for aromatic solvent 100 as CAS: Not avail.
| Ingredient Name | CAS |
| zinc phosphate | 7779-90-0, 7543-51-3 |
"Worst Case" computer-aided prediction of vapour components/concentrations:
Composite Exposure Standard for Mixture (TWA) (mg/m3): 405.4054 mg/m³
If the breathing zone concentration of ANY of the components listed below is exceeded,
"Worst Case" considerations deem the individual to be overexposed.
Component Breathing Zone ppm Breathing Zone mg/m3 Mixture Conc: (%).
Component Breathing zone Breathing Zone Mixture Conc
(ppm) (mg/m³) (%)
aromatic solvent 100 16.22 81.0811 5.0
mineral turpentine 54.05 324.3243 20.0
Operations which produce a spray/mist or fume/dust, introduce particulates to the
breathing zone.
If the breathing zone concentration of ANY of the components listed below is exceeded,
"Worst Case" considerations deem the individual to be overexposed.
At the "Composite Exposure Standard for Mixture" (TWA) (mg/m3): 25 mg/m³
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Issue Date: 7-Jul-2006
Print Date: 16-Mar-2007