SOLVER 4106 GALVA LINK

Chemwatch Independent Material Safety Data Sheet

Issue Date: 28-Sep-2008

C9317EC

CHEMWATCH 41176

Version No:5

Section 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

PRODUCT NAME

SOLVER 4106 GALVA LINK

PRODUCT USE

• Used according to manufacturer's directions.

SUPPLIER

Company: Solver Paints Pty Ltd          
Address:                                
560 Churchill Road                      
Kilburn                                 
SA, 5084                                
Australia                               
Telephone: +61 8 8368 1200              
Emergency Tel: 1800 039 008 (24 hours)  
Emergency Tel: +61 3 9573 3112          
Fax: +61 8 8368 1222                    
                                        

Section 2 - HAZARDS IDENTIFICATION

STATEMENT OF HAZARDOUS NATURE

NON-HAZARDOUS SUBSTANCE. NON-DANGEROUS GOODS. According to NOHSC Criteria, and ADG Code.

POISONS SCHEDULE

None

 

RISK

•None under normal operating conditions.

SAFETY

Safety Codes          Safety Phrases
S23                   • Do not breathe gas/fumes/vapour/spray.
S24                   • Avoid contact with skin.
S39                   • Wear eye/face protection.
S51                   • Use only in well ventilated areas.
S09                   • Keep container in a well ventilated place.
S07                   • Keep container tightly closed.
S26                   • In case of contact with eyes rinse with plenty of water
                      and contact Doctor or Poisons Information Centre.

 

Section 3 - COMPOSITION / INFORMATION ON INGREDIENTS

NAME CAS RN %
ammonium hydroxide 1336-21-6 <0.05^
acrylic copolymer emulsion 30-60
residual monomer trace
titanium dioxide 13463-67-7 10-30
mica 12001-26-2 1-10
anti corrosive pigments not regulated 1-10
additives unregulated <1.0
preservative - formaldehyde release type >0.1
NOTE: Manufacturer has supplied full ingredient
information to allow CHEMWATCH assessment.

Section 4 - FIRST AID MEASURES

SWALLOWED

· Immediately give a glass of water.
· First aid is not generally required. If in doubt, contact a Poisons Information Centre or a doctor.

EYE

• If this product comes in contact with the eyes:
· Wash out immediately with fresh running water.
· Ensure complete irrigation of the eye by keeping eyelids apart and away from eye and moving the eyelids by occasionally lifting the upper and lower lids.
· Seek medical attention without delay; if pain persists or recurs seek medical attention.
· Removal of contact lenses after an eye injury should only be undertaken by skilled personnel.

SKIN

• If skin contact occurs:
· Immediately remove all contaminated clothing, including footwear.
· Flush skin and hair with running water (and soap if available).
· Seek medical attention in event of irritation.

INHALED

· If fumes or combustion products are inhaled remove from contaminated area.
· Other measures are usually unnecessary.

NOTES TO PHYSICIAN

• Treat symptomatically.

Section 5 - FIRE FIGHTING MEASURES

EXTINGUISHING MEDIA

· There is no restriction on the type of extinguisher which may be used.
· Use extinguishing media suitable for surrounding area.

FIRE FIGHTING

· Alert Fire Brigade and tell them location and nature of hazard.
· Wear breathing apparatus plus protective gloves for fire only.
· Prevent, by any means available, spillage from entering drains or water courses.
· Use fire fighting procedures suitable for surrounding area.

FIRE/EXPLOSION HAZARD

· The material is not readily combustible under normal conditions.
· However, it will break down under fire conditions and the organic component may burn.
· Not considered to be a significant fire risk.
· Heat may cause expansion or decomposition with violent rupture of containers.

FIRE INCOMPATIBILITY

• None known.

HAZCHEM

None

PERSONAL PROTECTION

Glasses: Gloves: Respirator:
Chemical goggles. PVC chemical resistant type. Type K Filter of sufficient capacity

Section 6 - ACCIDENTAL RELEASE MEASURES

MINOR SPILLS

· Clean up waste regularly and abnormal spills immediately.
· Avoid breathing dust and contact with skin and eyes.
· Wear protective clothing, gloves, safety glasses and dust respirator.
· Use dry clean up procedures and avoid generating dust.

MAJOR SPILLS

• Moderate hazard.
· Clear area of personnel and move upwind.
· Alert Fire Brigade and tell them location and nature of hazard.
· Wear breathing apparatus plus protective gloves.
· Prevent, by any means available, spillage from entering drains or water course.

 

Personal Protective Equipment advice is contained in Section 8 of the MSDS.

Section 7 - HANDLING AND STORAGE

PROCEDURE FOR HANDLING

· Avoid all personal contact, including inhalation.
· Wear protective clothing when risk of exposure occurs.
· Use in a well-ventilated area.
· Avoid contact with moisture.
· DO NOT allow clothing wet with material to stay in contact with skin.

SUITABLE CONTAINER

· Polyethylene or polypropylene container.
· Packing as recommended by manufacturer.
· Check all containers are clearly labelled and free from leaks.

STORAGE INCOMPATIBILITY

• None known.

STORAGE REQUIREMENTS

· Store in original containers.
· Keep containers securely sealed.
· Store in a cool, dry, well-ventilated area.
· Store away from incompatible materials and foodstuff containers.

Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION

EXPOSURE CONTROLS

SourceMaterialTWA ppmTWA mg/m³STEL ppmSTEL mg/m³Notes
_________________________________________________________
Australia Exposure Standardsammonium hydroxide (Ammonia)25173524
Australia Exposure Standardstitanium dioxide (Titanium dioxide (a))10(see Chapter 14)
Australia Exposure Standardsmica (Mica)2.5(TWA (inspirable))

 

 

PERSONAL PROTECTION

RESPIRATOR

Type K Filter of sufficient capacity

EYE

· Safety glasses with side shields.
· Chemical goggles.
· Contact lenses may pose a special hazard; soft contact lenses may absorb and concentrate irritants. A written policy document, describing the wearing of lens or restrictions on use, should be created for each workplace or task. This should include a review of lens absorption and adsorption for the class of chemicals in use and an account of injury experience. Medical and first-aid personnel should be trained in their removal and suitable equipment should be readily available. In the event of chemical exposure, begin eye irrigation immediately and remove contact lens as soon as practicable. Lens should be removed at the first signs of eye redness or irritation - lens should be removed in a clean environment only after workers have washed hands thoroughly. [CDC NIOSH Current Intelligence Bulletin 59].

HANDS/FEET

· Wear chemical protective gloves, eg. PVC.
· Wear safety footwear or safety gumboots, eg. Rubber.
Suitability and durability of glove type is dependent on usage. Important factors in the selection of gloves include: such as:
· frequency and duration of contact,
· chemical resistance of glove material,
· glove thickness and
· dexterity.

OTHER

· Overalls.
· P.V.C. apron.
· Barrier cream.
· Skin cleansing cream.

ENGINEERING CONTROLS

• General exhaust is adequate under normal operating conditions. Local exhaust ventilation may be required in special circumstances.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES

APPEARANCE

White liquid; mixes with water. Ammonia and typical paint odour.

PHYSICAL PROPERTIES

Liquid.

 

StateLiquidMolecular WeightNot applicable
Melting Range (ºC)Not available.ViscosityNot available
Boiling Range (ºC)100 water.Solubility in water (g/L)Mixes with water
Flash Point (ºC)Non combustiblepH (1% solution)Not applicable
Decomposition Temp (ºC)Not available.pH (as supplied)8 - 10
Autoignition Temp (ºC)Not applicableVapour Pressure (kPa)As water
Upper Explosive Limit (%)Not applicableSpecific Gravity (water=1)1.20
Lower Explosive Limit (%)Not applicableRelative Vapour Density (air=1)Not available.
Volatile Component (%vol)50 approx.Evaporation RateSlow

 

Section 10 - CHEMICAL STABILITY AND REACTIVITY INFORMATION

CONDITIONS CONTRIBUTING TO INSTABILITY

· Presence of incompatible materials.
· Product is considered stable.
· Hazardous polymerisation will not occur.

For incompatible materials - refer to Section 7 - Handling and Storage.

Section 11 - TOXICOLOGICAL INFORMATION

POTENTIAL HEALTH EFFECTS

ACUTE HEALTH EFFECTS CHRONIC HEALTH EFFECTS
• Not applicable. • Not applicable.

TOXICITY AND IRRITATION

• unless otherwise specified data extracted from RTECS - Register of Toxic Effects of Chemical Substances.

• Not available. Refer to individual constituents. Content of ammonia is low and is not considered a health hazard under good working conditions, however continuous long term working in confined and poorly ventilated areas may cause irritation response, sore eyes/nose. TITANIUM DIOXIDE: • unless otherwise specified data extracted from RTECS - Register of Toxic Effects of Chemical Substances.
TOXICITY IRRITATION
Oral (Rat) LD50: >20000 mg/kg * Skin (human): 0.3 mg /3D (int)-Mild *
Oral (Mouse) LD50: >10000 mg/kg *
• The material may produce moderate eye irritation leading to inflammation. Repeated or prolonged exposure to irritants may produce conjunctivitis. The material may cause skin irritation after prolonged or repeated exposure and may produce a contact dermatitis (nonallergic). This form of dermatitis is often characterised by skin redness (erythema) and swelling epidermis. For titanium dioxide: Humans can be exposed to titanium dioxide via inhalation, ingestion or dermal contact. In human lungs, the clearance kinetics of titanium dioxide is poorly characterized relative to that in experimental animals. * IUCLID MICA: • No significant acute toxicological data identified in literature search.

 

CARCINOGEN

Titanium dioxideInternational Agency for Research on Cancer (IARC) - Agents Reviewed by the IARC MonographsGroup2B

 

Section 12 - ECOLOGICAL INFORMATION

No data

Ecotoxicity

IngredientPersistence: Water/SoilPersistence: AirBioaccumulationMobility
titanium dioxideHIGHLOWHIGH

 

Section 13 - DISPOSAL CONSIDERATIONS

· Containers may still present a chemical hazard/ danger when empty.
· Return to supplier for reuse/ recycling if possible.
Otherwise:
· If container can not be cleaned sufficiently well to ensure that residuals do not remain or if the container cannot be used to store the same product, then puncture containers, to prevent re-use, and bury at an authorised landfill.
· Where possible retain label warnings and MSDS and observe all notices pertaining to the product.
· Recycle wherever possible.
· Consult manufacturer for recycling options or consult local or regional waste management authority for disposal if no suitable treatment or disposal facility can be identified.
· Dispose of by: burial in a land-fill specifically licenced to accept chemical and / or pharmaceutical wastes or incineration in a licenced apparatus (after admixture with suitable combustible material).
· Decontaminate empty containers. Observe all label safeguards until containers are cleaned and destroyed.

Section 14 - TRANSPORTATION INFORMATION

HAZCHEM:

None  (ADG7)


NOT REGULATED FOR TRANSPORT OF DANGEROUS GOODS: ADG7, UN, IATA, IMDG

Section 15 - REGULATORY INFORMATION

POISONS SCHEDULE

None

REGULATIONS

Regulations for ingredients

titanium dioxide (CAS: 13463-67-7,1317-70-0,1317-80-2,12188-41-9,1309-63-3,100292-32-8,101239-53-6,116788-85-3,12000-59-8,12701-76-7,12767-65-6,12789-63-8,1344-29-2,185323-71-1,185828-91-5,188357-76-8,188357-79-1,195740-11-5,221548-98-7,224963-00-2,246178-32-5,252962-41-7,37230-92-5,37230-94-7,37230-95-8,37230-96-9,39320-58-6,39360-64-0,39379-02-7,416845-43-7,494848-07-6,494848-23-6,494851-77-3,494851-98-8,55068-84-3,55068-85-4,552316-51-5,62338-64-1,767341-00-4,97929-50-5,98084-96-9) is found on the following regulatory lists;

"Australia Exposure Standards","Australia High Volume Industrial Chemical List (HVICL)","Australia Inventory of Chemical Substances (AICS)","Australia Therapeutic Goods Administration (TGA) Substances that may be used as active ingredients in Listed medicines","Australia Therapeutic Goods Administration (TGA) Sunscreening agents permitted as active ingredients in listed products","CODEX General Standard for Food Additives (GSFA) - Additives Permitted for Use in Food in General, Unless Otherwise Specified, in Accordance with GMP","GESAMP/EHS Composite List - GESAMP Hazard Profiles","IMO IBC Code Chapter 17: Summary of minimum requirements","International Agency for Research on Cancer (IARC) - Agents Reviewed by the IARC Monographs","OECD Representative List of High Production Volume (HPV) Chemicals"

mica (CAS: 12001-26-2,129899-84-9,61076-94-6) is found on the following regulatory lists;

"Australia Exposure Standards","Australia Hazardous Substances","Australia Inventory of Chemical Substances (AICS)"

No data for Solver 4106 Galva Link (CW: 41176)

Section 16 - OTHER INFORMATION

INGREDIENTS WITH MULTIPLE CAS NUMBERS

Ingredient Name CAS
titanium dioxide 13463-67-7, 1317-70-0, 1317-80-2, 12188-41-9, 1309-63-3, 100292-32-8, 101239-53-6, 116788-85-3, 12000-59-8, 12701-76-7, 12767-65-6, 12789-63-8, 1344-29-2, 185323-71-1, 185828-91-5, 188357-76-8, 188357-79-1, 195740-11-5, 221548-98-7, 224963-00-2, 246178-32-5, 252962-41-7, 37230-92-5, 37230-94-7, 37230-95-8, 37230-96-9, 39320-58-6, 39360-64-0, 39379-02-7, 416845-43-7, 494848-07-6, 494848-23-6, 494851-77-3, 494851-98-8, 55068-84-3, 55068-85-4, 552316-51-5, 62338-64-1, 767341-00-4, 97929-50-5, 98084-96-9
mica 12001-26-2, 129899-84-9, 61076-94-6

 

• Classification of the preparation and its individual components has drawn on official and authoritative sources as well as independent review by the Chemwatch Classification committee using available literature references.
A list of reference resources used to assist the committee may be found at:
www.chemwatch.net/references.

 

• The (M)SDS is a Hazard Communication tool and should be used to assist in the Risk Assessment. Many factors determine whether the reported Hazards are Risks in the workplace or other settings.

 

This document is copyright. Apart from any fair dealing for the purposes of private study, research, review or
criticism, as permitted under the Copyright Act, no part may be reproduced by any process without written
permission from CHEMWATCH. TEL (+61 3) 9572 4700.

 

Issue Date: 28-Sep-2008

Print Date: 6-Aug-2010

 

 

This is the end of the MSDS.