Section 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

PRODUCT NAME

SOLVER 4608 BRITE GLO SCENIC FLAT BRILLIANT BLUE

PRODUCT USE

■ Used according to manufacturer's directions.

SUPPLIER

Company: Solver Paints Pty Ltd
Address:
560 Churchill Road
Kilburn
SA, 5084
Australia
Telephone: +61 8 8368 1200
Emergency Tel: 1800 039 008 (24 hours)
Emergency Tel: +61 3 9573 3112
Fax: +61 8 8368 1222

Section 2 - HAZARDS IDENTIFICATION

STATEMENT OF HAZARDOUS NATURE

NON-HAZARDOUS SUBSTANCE. NON-DANGEROUS GOODS. According to NOHSC Criteria, and ADG Code.

POISONS SCHEDULE

None

RISK

•None under normal operating conditions.

SAFETY

Safety Codes Safety Phrases
S23 ■ Do not breathe gas/fumes/vapour/spray.
S24 ■ Avoid contact with skin.

Section 3 - COMPOSITION / INFORMATION ON INGREDIENTS

Section 4 - FIRST AID MEASURES

SWALLOWED

· Immediately give a glass of water.
· First aid is not generally required. If in doubt, contact a Poisons Information Centre or a doctor.

EYE

■ If this product comes in contact with eyes:
· Wash out immediately with water.
· If irritation continues, seek medical attention.
· Removal of contact lenses after an eye injury should only be undertaken by skilled personnel.

SKIN

■ If skin contact occurs:
· Immediately remove all contaminated clothing, including footwear.
· Flush skin and hair with running water (and soap if available).
· Seek medical attention in event of irritation.

INHALED

· If fumes or combustion products are inhaled remove from contaminated area.
· Other measures are usually unnecessary.

NOTES TO PHYSICIAN

■ Treat symptomatically.

Section 5 - FIRE FIGHTING MEASURES

EXTINGUISHING MEDIA

· There is no restriction on the type of extinguisher which may be used.
· Use extinguishing media suitable for surrounding area.

FIRE FIGHTING

· Alert Fire Brigade and tell them location and nature of hazard.
· Wear breathing apparatus plus protective gloves for fire only.
· Prevent, by any means available, spillage from entering drains or water courses.
· Use fire fighting procedures suitable for surrounding area.

FIRE/EXPLOSION HAZARD

· Non combustible.
· Not considered a significant fire risk, however containers may burn., carbon dioxide (CO2), other pyrolysis products typical of burning organic material.
May emit poisonous fumes.

FIRE INCOMPATIBILITY

· Avoid contamination with oxidising agents i.e. nitrates, oxidising acids, chlorine bleaches, pool chlorine etc. as ignition may result.

HAZCHEM

None

PERSONAL PROTECTION

Glasses:           
Gloves:                       
Respirator:                              
Chemical goggles.  
PVC chemical resistant type.  
Type AK-P Filter of sufficient capacity  

Section 6 - ACCIDENTAL RELEASE MEASURES

MINOR SPILLS

· Clean up all spills immediately.
· Avoid breathing vapours and contact with skin and eyes.
· Control personal contact by using protective equipment.
· Contain and absorb spill with sand, earth, inert material or vermiculite.

MAJOR SPILLS

■ Moderate hazard.
· Clear area of personnel and move upwind.
· Alert Fire Brigade and tell them location and nature of hazard.
· Wear breathing apparatus plus protective gloves.
· Prevent, by any means available, spillage from entering drains or water course.

Personal Protective Equipment advice is contained in Section 8 of the MSDS.

Section 7 - HANDLING AND STORAGE

PROCEDURE FOR HANDLING

· Avoid all personal contact, including inhalation.
· Wear protective clothing when risk of exposure occurs.
· Use in a well-ventilated area.
· Avoid contact with moisture.
· DO NOT allow clothing wet with material to stay in contact with skin.

SUITABLE CONTAINER

· Polyethylene or polypropylene container.
· Packing as recommended by manufacturer.
· Check all containers are clearly labelled and free from leaks.

STORAGE INCOMPATIBILITY

· Avoid reaction with oxidising agents.

STORAGE REQUIREMENTS

· Store in original containers.
· Keep containers securely sealed.
· Store in a cool, dry, well-ventilated area.
· Store away from incompatible materials and foodstuff containers.

Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION

EXPOSURE CONTROLS

Source
Material
TWA ppm
TWA mg/m³
STEL ppm
STEL mg/m³
Notes
___________
___________
_______
_______
_______
_______
_______
Australia Exposure Standards
ammonium hydroxide (Ammonia)
25
17
35
24

Australia Exposure Standards
titanium dioxide (Titanium dioxide (a))
10
(see Chapter 14)

The following materials had no OELs on our records

  • pine oil: 
 CAS:8002-09-3

PERSONAL PROTECTION

RESPIRATOR

Type AK- P Filter of sufficient capacity

EYE

· Safety glasses with side shields.
· Chemical goggles.
· Contact lenses may pose a special hazard; soft contact lenses may absorb and concentrate irritants. A written policy document, describing the wearing of lens or
restrictions on use, should be created for each workplace or task. This should include a review of lens absorption and adsorption for the class of chemicals in use
and an account of injury experience. Medical and first- aid personnel should be trained in their removal and suitable equipment should be readily available. In the
event of chemical exposure, begin eye irrigation immediately and remove contact lens as soon as practicable. Lens should be removed at the first signs of eye redness
or irritation - lens should be removed in a clean environment only after workers have washed hands thoroughly. [CDC NIOSH Current Intelligence Bulletin 59].

HANDS/FEET

· Wear chemical protective gloves, eg. PVC.
· Wear safety footwear or safety gumboots, eg. Rubber.
NOTE:
· The material may produce skin sensitisation in predisposed individuals. Care must be taken, when removing gloves and other protective equipment, to avoid all
possible skin contact.
· Contaminated leather items, such as shoes, belts and watch- bands should be removed and destroyed.
Suitability and durability of glove type is dependent on usage. Important factors in the selection of gloves include: such as:
· frequency and duration of contact,
· chemical resistance of glove material,
· glove thickness and
· dexterity.

OTHER

· Overalls.
· P.V.C. apron.
· Barrier cream.
· Skin cleansing cream.

ENGINEERING CONTROLS

■ General exhaust is adequate under normal operating conditions. If risk of overexposure exists, wear SAA approved respirator.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES

APPEARANCE

Blue liquid paint; mixes with water. Mild ammonia and typical paint odour.
Acrylic copolymer emulsions may contain residual traces of odourous
monomer; the amounts remaining in compounded mixtures usually presents
a very low order of exposure.

PHYSICAL PROPERTIES

Liquid.
Does not mix with water.
Sinks in water.

State
Liquid
Molecular Weight
Not applicable
Melting Range (ºC)
Not available.
Viscosity
Not Available
Boiling Range (ºC)
100 water.
Solubility in water (g/L)
Immiscible
Flash Point (ºC)
Not Applicable
pH (1% solution)
Not applicable
Decomposition Temp (ºC)
Not Available
pH (as supplied)
9-10
Autoignition Temp (ºC)
Not Applicable
Vapour Pressure (kPa)
As water
Upper Explosive Limit (%)
Not Applicable
Specific Gravity (water=1)
1.15
Lower Explosive Limit (%)
Not Applicable
Relative Vapour Density (air=1)
Not available.
Volatile Component (%vol)
>60
Evaporation Rate
Not Available

Section 10 - CHEMICAL STABILITY AND REACTIVITY INFORMATION

CONDITIONS CONTRIBUTING TO INSTABILITY

· Presence of incompatible materials.
· Product is considered stable.
· Hazardous polymerisation will not occur.

For incompatible materials - refer to Section 7 - Handling and Storage.

Section 11 - TOXICOLOGICAL INFORMATION

POTENTIAL HEALTH EFFECTS

ACUTE HEALTH EFFECTS  
CHRONIC HEALTH EFFECTS  
■ Not applicable.     
■ Not applicable.       

TOXICITY AND IRRITATION

PINE OIL:
TITANIUM DIOXIDE:
■ unless otherwise specified data extracted from RTECS - Register of Toxic Effects of Chemical Substances.
■ unless otherwise specified data extracted from RTECS - Register of Toxic Effects of Chemical Substances.

■ Contact allergies quickly manifest themselves as contact eczema, more rarely as urticaria or Quincke' s oedema. The pathogenesis of contact eczema involves a cell-
mediated (T lymphocytes) immune reaction of the delayed type.
Content of ammonia is low and is not considered a significant hazard
under conditions of good occupational work practice, however continuous and
long term exposure may give rise to irritation response.
TITANIUM DIOXIDE:

TOXICITY                           
IRRITATION                             
Oral (Rat) LD50: >20000 mg/kg *    
Skin (human): 0.3 mg /3D (int)-Mild *  
Oral (Mouse) LD50: >10000 mg/kg *  
                                       

■ The material may produce moderate eye irritation leading to inflammation. Repeated or prolonged exposure to irritants may produce conjunctivitis.
The material may cause skin irritation after prolonged or repeated exposure and may produce a contact dermatitis (nonallergic). This form of dermatitis is often
characterised by skin redness (erythema) and swelling epidermis.
For titanium dioxide:
Humans can be exposed to titanium dioxide via inhalation, ingestion or dermal contact. In human lungs, the clearance kinetics of titanium dioxide is poorly
characterized relative to that in experimental animals.
* IUCLID
PINE OIL:

TOXICITY                          
IRRITATION                        
Oral (human) TDLo: 4700 mg/kg     
Skin (rabbit): 500 mg/24h-SEVERE  
Oral (rat) LD50: 3200 mg/kg       
                                  
Dermal (rabbit) LD50: 5000 mg/kg  
                                  

■ Contact allergies quickly manifest themselves as contact eczema, more rarely as urticaria or Quincke' s oedema. The pathogenesis of contact eczema involves a cell-
mediated (T lymphocytes) immune reaction of the delayed type.
Asthma- like symptoms may continue for months or even years after exposure to the material ceases. This may be due to a non- allergenic condition known as reactive
airways dysfunction syndrome (RADS) which can occur following exposure to high levels of highly irritating compound.
Camphor appears to have moderate acute oral toxicity, with an LD50 of 1310 mg/kg in mice. It demonstrated moderate to high toxicity in acute inhalation studies(450
mg/m3 (72 ppm) in mice and 500 mg/m3 (80 ppm) in rats).
The material may produce severe skin irritation after prolonged or repeated exposure, and may produce a contact dermatitis (nonallergic). This form of dermatitis is
often characterised by skin redness (erythema) thickening of the epidermis.<</>.
d- Limonene is readily absorbed by inhalation and ingestion. Dermal absorption is reported to be lower than by the inhalation route.
Limonene exhibits low acute toxicity by all three routes in animals.
For terpenoid tertiary alcohols and their related esters:
Substances assigned to this category, as part of the HPV Challenge Program, possess close structural relationships, similar physicochemical properties and
participate in the same pathways of metabolic detoxification and have similar toxicologic potential.
Acute Toxicity: Oral and dermal LD50 values for members of this chemical category indicate a low order of both oral and dermal toxicity. All rabbit dermal, and mouse
and rat oral LD50 values exceed 2000 mg/kg with the majority of values greater than 5000 mg/kg <</>.

CARCINOGEN

Titanium dioxide
International Agency for Research on Cancer (IARC) - Agents Reviewed by the IARC Monographs
Group
2B

Section 12 - ECOLOGICAL INFORMATION

No data

Ecotoxicity

Ingredient
Persistence: Water/Soil
Persistence: Air
Bioaccumulation
Mobility
titanium dioxide
HIGH
LOW
HIGH

Section 13 - DISPOSAL CONSIDERATIONS

· Recycle wherever possible.
· Consult manufacturer for recycling options or consult local or regional waste management authority for disposal if no suitable treatment or disposal facility can be identified.
· Dispose of by: burial in a land-fill specifically licenced to accept chemical and / or pharmaceutical wastes or incineration in a licenced apparatus (after admixture with suitable combustible material).
· Decontaminate empty containers. Observe all label safeguards until containers are cleaned and destroyed.

Section 14 - TRANSPORTATION INFORMATION

HAZCHEM:

None (ADG7)
NOT REGULATED FOR TRANSPORT OF DANGEROUS GOODS: ADG7, UN, IATA, IMDG

Section 15 - REGULATORY INFORMATION

POISONS SCHEDULE

None

REGULATIONS

Regulations for ingredients

titanium dioxide (CAS: 13463-67-7,1317-70-0,1317-80-2,12188-41-9,1309-63-3,100292-32-8,101239-53-6,116788-85-3,12000-59-8,12701-76-7,12767-65-6,12789-63-8,1344-29-2,185323-71-1,185828-91-5,188357-76-8,188357-79-1,195740-11-5,221548-98-7,224963-00-2,246178-32-5,252962-41-7,37230-92-5,37230-94-7,37230-95-8,37230-96-9,39320-58-6,39360-64-0,39379-02-7,416845-43-7,494848-07-6,494848-23-6,494851-77-3,494851-98-8,55068-84-3,55068-85-4,552316-51-5,62338-64-1,767341-00-4,97929-50-5,98084-96-9) is found on the following regulatory lists;

"Australia Exposure Standards","Australia High Volume Industrial Chemical List (HVICL)","Australia Inventory of Chemical Substances (AICS)","Australia Therapeutic Goods Administration (TGA) Substances that may be used as active ingredients in Listed medicines","Australia Therapeutic Goods Administration (TGA) Sunscreening agents permitted as active ingredients in listed products","CODEX General Standard for Food Additives (GSFA) - Additives Permitted for Use in Food in General, Unless Otherwise Specified, in Accordance with GMP","GESAMP/EHS Composite List - GESAMP Hazard Profiles","IMO IBC Code Chapter 17: Summary of minimum requirements","International Agency for Research on Cancer (IARC) - Agents Reviewed by the IARC Monographs","OECD Representative List of High Production Volume (HPV) Chemicals"

pine oil (CAS: 8002-09-3) is found on the following regulatory lists;

"Australia Inventory of Chemical Substances (AICS)","Australia Standard for the Uniform Scheduling of Drugs and Poisons (SUSDP) - Schedule 5","Australia Standard for the Uniform Scheduling of Drugs and Poisons (SUSDP) - Schedule 6","GESAMP/EHS Composite List - GESAMP Hazard Profiles","IMO IBC Code Chapter 17: Summary of minimum requirements","OECD Representative List of High Production Volume (HPV) Chemicals"

No data for Solver 4608 Brite Glo Scenic Flat Brilliant Blue (CW: 40120)

Section 16 - OTHER INFORMATION

INGREDIENTS WITH MULTIPLE CAS NUMBERS

Ingredient Name   
CAS                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                
titanium dioxide  
13463-67-7,  1317-70-0,  1317-80-2,  12188-41-9,  1309-63-3,  100292-32-8,  101239-53-6,  116788-85-3,  12000-59-8,  12701-76-7,  12767-65-6,  12789-63-8,  1344-29-2,  185323-71-1,  185828-91-5,  188357-76-8,  188357-79-1,  195740-11-5,  221548-98-7,  224963-00-2,  246178-32-5,  252962-41-7,  37230-92-5,  37230-94-7,  37230-95-8,  37230-96-9,  39320-58-6,  39360-64-0,  39379-02-7,  416845-43-7,  494848-07-6,  494848-23-6,  494851-77-3,  494851-98-8,  55068-84-3,  55068-85-4,  552316-51-5,  62338-64-1,  767341-00-4,  97929-50-5,  98084-96-9  

■ Classification of the preparation and its individual components has drawn on official and authoritative sources as well as independent review by the Chemwatch Classification committee using available literature references.
A list of reference resources used to assist the committee may be found at:
www.chemwatch.net/references.

■ The (M)SDS is a Hazard Communication tool and should be used to assist in the Risk Assessment. Many factors determine whether the reported Hazards are Risks in the workplace or other settings.

This document is copyright. Apart from any fair dealing for the purposes of private study, research, review or
criticism, as permitted under the Copyright Act, no part may be reproduced by any process without written
permission from CHEMWATCH. TEL (+61 3) 9572 4700.

Issue Date: 3-Jul-2008

Print Date: 24-Aug-2010

This is the end of the MSDS.