SOLVER 4865 SUPER DRY A/C STRUCTURAL PRIMER RED OXIDE
Chemwatch Independent Material Safety Data Sheet
Issue Date: 8-Jul-2008
C9317EC
CHEMWATCH 26136
Version No:4
SOLVER 4865 SUPER DRY A/C STRUCTURAL PRIMER RED OXIDE
PAINT
■ Used according to manufacturer's directions.
Company: Solver Paints Pty Ltd Address: 560 Churchill Road Kilburn SA, 5084 Australia Telephone: +61 8 8368 1200 Emergency Tel: 1800 039 008 (24 hours) Emergency Tel: +61 3 9573 3112 Fax: +61 8 8368 1222
HAZARDOUS SUBSTANCE. DANGEROUS GOODS. According to NOHSC Criteria, and ADG Code.
S5
Risk Codes Risk Phrases R11 ■ Highly flammable. R37/38 ■ Irritating to respiratory system and skin. R51/53 ■ Toxic to aquatic organisms, may cause long- term adverse effects in the aquatic environment. R65 ■ HARMFUL- May cause lung damage if swallowed. R67 ■ Vapours may cause drowsiness and dizziness.
Safety Codes Safety Phrases S36 ■ Wear suitable protective clothing. S51 ■ Use only in well ventilated areas. S401 ■ To clean the floor and all objects contaminated by this material use water and detergent. S35 ■ This material and its container must be disposed of in a safe way. S13 ■ Keep away from food drink and animal feeding stuffs. S46 ■ If swallowed IMMEDIATELY contact Doctor or Poisons Information Centre. (show this container or label). S57 ■ Use appropriate container to avoid environmental contamination. S61 ■ Avoid release to the environment. Refer to special instructions/Safety data sheets. S60 ■ This material and its container must be disposed of as hazardous waste.
| NAME | CAS RN | % |
| white spirit | 8052-41-3. | 10-30 |
| alkyd resin solution | Various | 30-60 |
| naphtha petroleum, light aromatic solvent | 64742-95-6. | 10-30 |
| ferric oxide | 1309-37-1 | 10-30 |
| inert pigment silica free unregulated | 10-30 | |
| additives non regulated as | <1.0 | |
| dispersant anti skinning agent drier | ||
| NOTE: Manufacturer has supplied full ingredient | ||
| information for CHEMWATCH assessment. |
· If swallowed do NOT induce vomiting.
· If vomiting occurs, lean patient forward or place on left side (head-down position, if possible) to maintain open airway and prevent aspiration.
· Observe the patient carefully.
· Never give liquid to a person showing signs of being sleepy or with reduced awareness; i.e. becoming unconscious.
· Avoid giving milk or oils.
· Avoid giving alcohol.
· If spontaneous vomiting appears imminent or occurs, hold patient's head down, lower than their hips to help avoid possible aspiration of vomitus.
■ If this product comes in contact with the eyes:
· Wash out immediately with fresh running water.
· Ensure complete irrigation of the eye by keeping eyelids apart and away from eye and moving the eyelids by occasionally lifting the upper and lower lids.
· Seek medical attention without delay; if pain persists or recurs seek medical attention.
· Removal of contact lenses after an eye injury should only be undertaken by skilled personnel.
■ If skin contact occurs:
· Immediately remove all contaminated clothing, including footwear.
· Flush skin and hair with running water (and soap if available).
· Seek medical attention in event of irritation.
· If fumes or combustion products are inhaled remove from contaminated area.
· Lay patient down. Keep warm and rested.
· Prostheses such as false teeth, which may block airway, should be removed, where possible, prior to initiating first aid procedures.
· Apply artificial respiration if not breathing, preferably with a demand valve resuscitator, bag-valve mask device, or pocket mask as trained. Perform CPR if necessary.
■ Any material aspirated during vomiting may produce lung injury. Therefore emesis should not be induced mechanically or pharmacologically. For acute or short term repeated exposures to petroleum distillates or related hydrocarbons: · Primary threat to life, from pure petroleum distillate ingestion and/or inhalation, is respiratory failure. · Patients should be quickly evaluated for signs of respiratory distress (e.g. cyanosis, tachypnoea, intercostal retraction, obtundation) and given oxygen. Patients with inadequate tidal volumes or poor arterial blood gases (pO2 50 mm Hg) should be intubated. · Arrhythmias complicate some hydrocarbon ingestion and/or inhalation and electrocardiographic evidence of myocardial injury has been reported; intravenous lines and cardiac monitors should be established in obviously symptomatic patients. The lungs excrete inhaled solvents, so that hyperventilation improves clearance. · A chest x- ray should be taken immediately after stabilisation of breathing and circulation to document aspiration and detect the presence of pneumothorax. Treat symptomatically.
· Foam. · Dry chemical powder. · BCF (where regulations permit). · Carbon dioxide.
· Alert Fire Brigade and tell them location and nature of hazard. · May be violently or explosively reactive. · Wear breathing apparatus plus protective gloves. · Prevent, by any means available, spillage from entering drains or water course. When any large container (including road and rail tankers) is involved in a fire, consider evacuation by 500 metres in all directions.
· Liquid and vapour are highly flammable. · Severe fire hazard when exposed to heat, flame and/or oxidisers. · Vapour may travel a considerable distance to source of ignition. · Heating may cause expansion or decomposition leading to violent rupture of containers. Combustion products include: carbon dioxide (CO2), other pyrolysis products typical of burning organic material. May emit clouds of acrid smoke.
· Avoid contamination with oxidising agents i.e. nitrates, oxidising acids, chlorine bleaches, pool chlorine etc. as ignition may result.
•3YE
| Glasses: | Gloves: | Respirator: |
| Chemical goggles. | PVC chemical resistant type. | Type A-P Filter of sufficient capacity |
· Remove all ignition sources. · Clean up all spills immediately. · Avoid breathing vapours and contact with skin and eyes. · Control personal contact by using protective equipment.
· Clear area of personnel and move upwind. · Alert Fire Brigade and tell them location and nature of hazard. · May be violently or explosively reactive. · Wear breathing apparatus plus protective gloves.
Personal Protective Equipment advice is contained in Section 8 of the MSDS.
· Containers, even those that have been emptied, may contain explosive vapours.
· Do NOT cut, drill, grind, weld or perform similar operations on or near containers.
· DO NOT allow clothing wet with material to stay in contact with skin.
· Electrostatic discharge may be generated during pumping - this may result in fire.
· Ensure electrical continuity by bonding and grounding (earthing) all equipment.
· Restrict line velocity during pumping in order to avoid generation of electrostatic discharge (<=1 m/sec until fill pipe submerged to twice its diameter, then <= 7 m/sec).
· Avoid splash filling.
· Avoid all personal contact, including inhalation.
· Wear protective clothing when risk of exposure occurs.
· Use in a well-ventilated area.
· Prevent concentration in hollows and sumps.
· Packing as supplied by manufacturer.
· Plastic containers may only be used if approved for flammable liquid.
· Check that containers are clearly labelled and free from leaks.
· For low viscosity materials (i) : Drums and jerry cans must be of the non-removable head type. (ii) : Where a can is to be used as an inner package, the can must have a screwed enclosure.
· For materials with a viscosity of at least 2680 cSt. (23 deg. C)
· For manufactured product having a viscosity of at least 250 cSt. (23 deg. C)
· Manufactured product that requires stirring before use and having a viscosity of at least 20 cSt (25 deg. C).
· Avoid reaction with oxidising agents.
Avoid storage with strong oxidisers.
· Store in original containers in approved flame-proof area.
· No smoking, naked lights, heat or ignition sources.
· DO NOT store in pits, depressions, basements or areas where vapours may be trapped.
· Keep containers securely sealed.
| Source | Material | TWA mg/m³ | Notes |
| ___________ | ___________ | _______ | _______ |
| Australia Exposure Standards | white spirit (White spirits) | 790 | (see Chapter 16) |
| Australia Exposure Standards | white spirit (Petrol (gasoline)) | 900 | (see Chapter 16) |
| Australia Exposure Standards | naphtha petroleum, light aromatic solvent (Petrol (gasoline)) | 900 | (see Chapter 16) |
| Australia Exposure Standards | ferric oxide (Iron oxide fume (Fe2O3) (as Fe)) | 5 | (see Chapter 17) |
Type A- P Filter of sufficient capacity
· Safety glasses with side shields. · Chemical goggles. · Contact lenses may pose a special hazard; soft contact lenses may absorb and concentrate irritants. A written policy document, describing the wearing of lens or restrictions on use, should be created for each workplace or task. This should include a review of lens absorption and adsorption for the class of chemicals in use and an account of injury experience. Medical and first- aid personnel should be trained in their removal and suitable equipment should be readily available. In the event of chemical exposure, begin eye irrigation immediately and remove contact lens as soon as practicable. Lens should be removed at the first signs of eye redness or irritation - lens should be removed in a clean environment only after workers have washed hands thoroughly. [CDC NIOSH Current Intelligence Bulletin 59].
· Wear chemical protective gloves, eg. PVC. · Wear safety footwear or safety gumboots, eg. Rubber. Suitability and durability of glove type is dependent on usage. Important factors in the selection of gloves include: such as: · frequency and duration of contact, · chemical resistance of glove material, · glove thickness and · dexterity. · Polyethylene gloves. · DO NOT use solvent to clean the skin.
· Overalls. · PVC Apron. · PVC protective suit may be required if exposure severe. · Eyewash unit.
■ For flammable liquids and flammable gases, local exhaust ventilation or a process enclosure ventilation system may be required. Ventilation equipment should be explosion- resistant. Air contaminants generated in the workplace possess varying " escape" velocities which, in turn, determine the " capture velocities" of fresh circulating air required to effectively remove the contaminant.
| Type of Contaminant: | Air Speed: |
| solvent, vapours, degreasing etc., evaporating from tank (in still air). | 0.25- 0.5 m/s (50-100 f/min.) |
| aerosols, fumes from pouring operations, intermittent container filling, low speed conveyer transfers, welding, spray drift, plating acid fumes, pickling (released at low velocity into zone of active generation) | 0.5- 1 m/s (100-200 f/min.) |
| direct spray, spray painting in shallow booths, drum filling, conveyer loading, crusher dusts, gas discharge (active generation into zone of rapid air motion) | 1- 2.5 m/s (200-500 f/min.) |
Red highly flammable liquid; does not mix with water. Strong solvent smell. Mixes with organic solvents.
Liquid.
Does not mix with water.
Sinks in water.
| State | Liquid | Molecular Weight | Not Applicable |
| Melting Range (ºC) | Not Available | Viscosity | Not Available |
| Boiling Range (ºC) | Not Available | Solubility in water (g/L) | Immiscible |
| Flash Point (ºC) | 4 toluene | pH (1% solution) | Not Applicable |
| Decomposition Temp (ºC) | Not Available | pH (as supplied) | Not Applicable |
| Autoignition Temp (ºC) | Not Available | Vapour Pressure (kPa) | Not Available |
| Upper Explosive Limit (%) | 7.8 toluene | Specific Gravity (water=1) | 1.10 approx |
| Lower Explosive Limit (%) | 1.2 toluene | Relative Vapour Density (air=1) | > 2 |
| Volatile Component (%vol) | 50 approx | Evaporation Rate | Not Available |
· Presence of incompatible materials.
· Product is considered stable.
· Hazardous polymerisation will not occur.
For incompatible materials - refer to Section 7 - Handling and Storage.
| ACUTE HEALTH EFFECTS | CHRONIC HEALTH EFFECTS |
| ■ HARMFUL-May cause lung damage if swallowed. | ■ Not applicable. |
| ■ Irritating to respiratory system and skin. | |
| ■ Vapours may cause dizziness or suffocation. | |
| ■ Vapours may cause drowsiness and dizziness. |
NAPHTHA PETROLEUM, LIGHT AROMATIC SOLVENT: FERRIC OXIDE: WHITE SPIRIT: ■ unless otherwise specified data extracted from RTECS - Register of Toxic Effects of Chemical Substances. NAPHTHA PETROLEUM, LIGHT AROMATIC SOLVENT: WHITE SPIRIT: ■ for petroleum: This product contains benzene which is known to cause acute myeloid leukaemia and n- hexane which has been shown to metabolize to compounds which are neuropathic. This product contains toluene. This product contains ethyl benzene and naphthalene from which there is evidence of tumours in rodents Carcinogenicity: Inhalation exposure to mice causes liver tumours, which are not considered relevant to humans. ■ unless otherwise specified data extracted from RTECS - Register of Toxic Effects of Chemical Substances.
| TOXICITY | IRRITATION |
| Inhalation (human) TCLo: 600 mg/m³/8h | Nil Reported |
| Oral (rat) LD50: >5000 mg/kg | Eye (human): 470 ppm/15m |
| Inhalation (rat) LC50: >5500 mg/m³/4h | Eye (rabbit): 500 mg/24h Moderate |
| TOXICITY | IRRITATION |
| Oral (rat) LD50: >5000 mg/kg * | Nil Reported |
| Inhalation (rat) LC50: >3670 ppm/8 h * | |
| Inhalation (rat) TCLo: 1320 ppm/6h/90D-I |
| Gasoline (NB: Overall evaluation upgraded from 3 to 2B with supporting evidence from other relevant data) | International Agency for Research on Cancer (IARC) - Agents Reviewed by the IARC Monographs | Group | 2B |
| Crude oil | International Agency for Research on Cancer (IARC) - Agents Reviewed by the IARC Monographs | Group | 3 |
| Ferric oxide | International Agency for Research on Cancer (IARC) - Agents Reviewed by the IARC Monographs | Group | 3 |
Toxic to aquatic organisms, may cause long- term adverse effects in the aquatic environment. This material and its container must be disposed of as hazardous waste. Avoid release to the environment. Refer to special instructions/ safety data sheets.
· DO NOT allow wash water from cleaning or process equipment to enter drains.
· It may be necessary to collect all wash water for treatment before disposal.
· In all cases disposal to sewer may be subject to local laws and regulations and these should be considered first.
· Where in doubt contact the responsible authority.
· Recycle wherever possible.
· Consult manufacturer for recycling options or consult local or regional waste management authority for disposal if no suitable treatment or disposal facility can be identified.
· Dispose of by: burial in a land-fill specifically licenced to accept chemical and / or pharmaceutical wastes or Incineration in a licenced apparatus (after admixture with suitable combustible material).
· Decontaminate empty containers. Observe all label safeguards until containers are cleaned and destroyed.
Labels Required: FLAMMABLE LIQUID
●3YE (ADG7)
| Class or division: | 3 | Subsidiary risk: | None |
| UN No.: | 1263 | UN packing group: | II |
| Special provisions: | 163 | Packing Instructions: | None |
| Limited quantities: | 5 L | Portable tanks and bulk containers - Instructions: | T4 |
| Portable tanks and bulk containers - Special provisions: | TP1; TP8; TP28 | Packagings and IBCs - Packing instruction: | P001; IBC02 |
| Packagings and IBCs - Special packing provisions: | PP1 |
| Class or division: | 3 | Subsidiary risk: | None |
| UN No.: | 1263 | UN packing group: | II |
| ICAO/IATA Class: | 3 | ICAO/IATA Subrisk: | None |
| UN/ID Number: | 1263 | Packing Group: | II |
| Special provisions: | A3 | ||
| IMDG Class: | 3 | IMDG Subrisk: | None |
| UN Number: | 1263 | Packing Group: | II |
| EMS Number: | F-E , S-E | Special provisions: | 163 |
| Limited Quantities: | 5 L |
S5
Regulations for ingredients
"Australia Exposure Standards","Australia Hazardous Substances","Australia Inventory of Chemical Substances (AICS)","Australia Standard for the Uniform Scheduling of Drugs and Poisons (SUSDP) - Appendix E (Part 2)","GESAMP/EHS Composite List - GESAMP Hazard Profiles","IMO IBC Code Chapter 17: Summary of minimum requirements","IMO Provisional Categorization of Liquid Substances - List 2: Pollutant only mixtures containing at least 99% by weight of components already assessed by IMO","International Council of Chemical Associations (ICCA) - High Production Volume List","OECD Representative List of High Production Volume (HPV) Chemicals"
"Australia Hazardous Substances","Australia High Volume Industrial Chemical List (HVICL)","Australia Inventory of Chemical Substances (AICS)","International Council of Chemical Associations (ICCA) - High Production Volume List","OECD Representative List of High Production Volume (HPV) Chemicals"
"Australia Exposure Standards","Australia High Volume Industrial Chemical List (HVICL)","Australia Inventory of Chemical Substances (AICS)","International Agency for Research on Cancer (IARC) - Agents Reviewed by the IARC Monographs","International Council of Chemical Associations (ICCA) - High Production Volume List","OECD Representative List of High Production Volume (HPV) Chemicals"
No data for alkyd resin solution (CAS: , Various)
| Ingredient Name | CAS |
| white spirit | 8052-41-3, 8042-47-5 |
■ Classification of the preparation and its individual components has drawn on official and authoritative sources as well as independent review by the Chemwatch Classification committee using available literature references.
A list of reference resources used to assist the committee may be found at:
www.chemwatch.net/references.
■ The (M)SDS is a Hazard Communication tool and should be used to assist in the Risk Assessment. Many factors determine whether the reported Hazards are Risks in the workplace or other settings.
This document is copyright. Apart from any fair dealing for the purposes of private study, research, review or
criticism, as permitted under the Copyright Act, no part may be reproduced by any process without written
permission from CHEMWATCH. TEL (+61 3) 9572 4700.
Issue Date: 8-Jul-2008
Print Date: 24-Aug-2010
This is the end of the MSDS.