SOLVER 4651 ANTI FUNGUS ADDITIVE
Chemwatch Independent Material Safety Data Sheet
Issue Date: 27-Feb-2009
C9317EC
CHEMWATCH 13290
Version No:4
SOLVER 4651 ANTI FUNGUS ADDITIVE
ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S.(contains 2-octyl-4-isothiazolin-3-one)
■ Used according to manufacturer's directions.
Company: Solver Paints Pty Ltd Address: 560 Churchill Road Kilburn SA, 5084 Australia Telephone: +61 8 8368 1200 Emergency Tel: 1800 039 008 (24 hours) Emergency Tel: +61 3 9573 3112 Fax: +61 8 8368 1222
HAZARDOUS SUBSTANCE. DANGEROUS GOODS. According to NOHSC Criteria, and ADG Code.
COMBUSTIBLE LIQUID, regulated under AS1940 for Bulk Storage purposes only.
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Risk Codes Risk Phrases R20/21 ■ Harmful by inhalation and in contact with skin. R36/38 ■ Irritating to eyes and skin. R43 ■ May cause SENSITISATION by skin contact. R51/53 ■ Toxic to aquatic organisms, may cause long- term adverse effects in the aquatic environment.
Safety Codes Safety Phrases S36 ■ Wear suitable protective clothing. S401 ■ To clean the floor and all objects contaminated by this material use water and detergent. S35 ■ This material and its container must be disposed of in a safe way. S13 ■ Keep away from food drink and animal feeding stuffs. S46 ■ If swallowed IMMEDIATELY contact Doctor or Poisons Information Centre. (show this container or label). S57 ■ Use appropriate container to avoid environmental contamination. S61 ■ Avoid release to the environment. Refer to special instructions/Safety data sheets. S60 ■ This material and its container must be disposed of as hazardous waste.
| NAME | CAS RN | % |
| propylene glycol | 57-55-6 | >60 |
| 2- octyl- 4- isothiazolin- 3- one | 26530-20-1 | 1-9 |
· If swallowed do NOT induce vomiting.
· If vomiting occurs, lean patient forward or place on left side (head-down position, if possible) to maintain open airway and prevent aspiration.
· Observe the patient carefully.
· Never give liquid to a person showing signs of being sleepy or with reduced awareness; i.e. becoming unconscious.
· If spontaneous vomiting appears imminent or occurs, hold patient's head down, lower than their hips to help avoid possible aspiration of vomitus.
■ If this product comes in contact with the eyes:
· Wash out immediately with fresh running water.
· Ensure complete irrigation of the eye by keeping eyelids apart and away from eye and moving the eyelids by occasionally lifting the upper and lower lids.
· Seek medical attention without delay; if pain persists or recurs seek medical attention.
· Removal of contact lenses after an eye injury should only be undertaken by skilled personnel.
■ If skin contact occurs:
· Immediately remove all contaminated clothing, including footwear.
· Flush skin and hair with running water (and soap if available).
· Seek medical attention in event of irritation.
· If fumes or combustion products are inhaled remove from contaminated area.
· Lay patient down. Keep warm and rested.
· Prostheses such as false teeth, which may block airway, should be removed, where possible, prior to initiating first aid procedures.
· Apply artificial respiration if not breathing, preferably with a demand valve resuscitator, bag-valve mask device, or pocket mask as trained. Perform CPR if necessary.
■ To treat poisoning by the higher aliphatic alcohols (up to C7): · Gastric lavage with copious amounts of water. · It may be beneficial to instill 60 ml of mineral oil into the stomach. · Oxygen and artificial respiration as needed. · Electrolyte balance: it may be useful to start 500 ml. M/6 sodium bicarbonate intravenously but maintain a cautious and conservative attitude toward electrolyte replacement unless shock or severe acidosis threatens. Propylene glycol is primarily a CNS depressant in large doses and may cause hypoglycaemia, lactic acidosis and seizures. · The usual measures are supportive care and decontamination (Ipecac/ lavage/ activated charcoal/ cathartics), within 2 hours of exposure should suffice. · Check the anion gap, arterial pH, renal function and glucose levels. Ellenhorn and Barceloux: Medical Toxicology.
· Alcohol stable foam. · Dry chemical powder. · BCF (where regulations permit). · Carbon dioxide.
· Alert Fire Brigade and tell them location and nature of hazard. · Wear full body protective clothing with breathing apparatus. · Prevent, by any means available, spillage from entering drains or water course. · Use water delivered as a fine spray to control fire and cool adjacent area. When any large container (including road and rail tankers) is involved in a fire, consider evacuation by 100 metres in all directions.
· Combustible. · Slight fire hazard when exposed to heat or flame. · Heating may cause expansion or decomposition leading to violent rupture of containers. · On combustion, may emit toxic fumes of carbon monoxide (CO). Combustion products include: carbon dioxide (CO2), nitrogen oxides (NOx), sulfur oxides (SOx), other pyrolysis products typical of burning organic material.
· Avoid contamination with oxidising agents i.e. nitrates, oxidising acids, chlorine bleaches, pool chlorine etc. as ignition may result.
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Gas tight chemical resistant suit.
■ Environmental hazard - contain spillage. · Clean up all spills immediately. · Avoid breathing vapours and contact with skin and eyes. · Control personal contact by using protective equipment. · Contain and absorb spill with sand, earth, inert material or vermiculite.
■ Environmental hazard - contain spillage. · Absorb or contain isothiazolinone liquid spills with sand, earth, inert material or vermiculite. · The absorbent (and surface soil to a depth sufficient to remove all of the biocide) should be shovelled into a drum and treated with an 11% solution of sodium metabisulfite (Na2S2O5) or sodium bisulfite (NaHSO3), or 12% sodium sulfite (Na2SO3) and 8% hydrochloric acid (HCl). · Glutathione has also been used to inactivate the isothiazolinones. · Use 20 volumes of decontaminating solution for each volume of biocide, and let containers stand for at least 30 minutes to deactivate microbicide before disposal.
Personal Protective Equipment advice is contained in Section 8 of the MSDS.
· DO NOT allow clothing wet with material to stay in contact with skin.
· Avoid all personal contact, including inhalation.
· Wear protective clothing when risk of exposure occurs.
· Use in a well-ventilated area.
· Prevent concentration in hollows and sumps.
· Metal can or drum
· Packaging as recommended by manufacturer.
· Check all containers are clearly labelled and free from leaks.
■ Alcohols
· are incompatible with strong acids, acid chlorides, acid anhydrides, oxidising and reducing agents.
· reacts, possibly violently, with alkaline metals and alkaline earth metals to produce hydrogen
· react with strong acids, strong caustics, aliphatic amines, isocyanates, acetaldehyde, benzoyl peroxide, chromic acid, chromium oxide, dialkylzincs, dichlorine oxide, ethylene oxide, hypochlorous acid, isopropyl chlorocarbonate, lithium tetrahydroaluminate, nitrogen dioxide, pentafluoroguanidine, phosphorus halides, phosphorus pentasulfide, tangerine oil, triethylaluminium, triisobutylaluminium
· should not be heated above 49 deg. C. when in contact with aluminium equipment.
Chemical Name Container Type
Propylene Glycol " Acetal (Delrinr)" , Bronze, " Buna N (Nitrile)" , " Cast iron" ,
CPVC, " Fluorocarbon (FKM)" , Hypalonr, NORYLr, Nylon, Polycarbonate,
PVC, Tygonr, Vitonr
· Material is hygroscopic, i.e. absorbs moisture from the air. Keep containers well sealed in storage.
· Store in original containers.
· Keep containers securely sealed.
· Store in a cool, dry, well-ventilated area.
· Store away from incompatible materials and foodstuff containers.
| Source | Material | TWA ppm | TWA mg/m³ |
| ___________ | ___________ | _______ | _______ |
| Australia Exposure Standards | Solver 4651 Anti Fungus Additive (Propane-1,2-diol: particulates only) | 10 | |
| Australia Exposure Standards | Solver 4651 Anti Fungus Additive (Propane-1,2-diol total: (vapour & particulates)) | 150 | 474 |
| Australia Exposure Standards | propylene glycol (Propane-1,2-diol: particulates only) | 10 | |
| Australia Exposure Standards | propylene glycol (Propane-1,2-diol total: (vapour & particulates)) | 150 | 474 |
The following materials had no OELs on our records
| • 2-octyl-4-isothiazolin-3-one: | CAS:26530-20-1 |
Type A- P Filter of sufficient capacity
· Safety glasses with side shields. · Chemical goggles. · Contact lenses may pose a special hazard; soft contact lenses may absorb and concentrate irritants. A written policy document, describing the wearing of lens or restrictions on use, should be created for each workplace or task. This should include a review of lens absorption and adsorption for the class of chemicals in use and an account of injury experience. Medical and first- aid personnel should be trained in their removal and suitable equipment should be readily available. In the event of chemical exposure, begin eye irrigation immediately and remove contact lens as soon as practicable. Lens should be removed at the first signs of eye redness or irritation - lens should be removed in a clean environment only after workers have washed hands thoroughly. [CDC NIOSH Current Intelligence Bulletin 59].
· Wear chemical protective gloves, eg. PVC. · Wear safety footwear or safety gumboots, eg. Rubber. NOTE: · The material may produce skin sensitisation in predisposed individuals. Care must be taken, when removing gloves and other protective equipment, to avoid all possible skin contact. · Contaminated leather items, such as shoes, belts and watch- bands should be removed and destroyed. Suitability and durability of glove type is dependent on usage. Important factors in the selection of gloves include: such as: · frequency and duration of contact, · chemical resistance of glove material, · glove thickness and · dexterity. · Butyl rubber gloves. · Nitrile rubber gloves.
· Overalls. · P.V.C. apron. · Barrier cream. · Skin cleansing cream.
■ General exhaust is adequate under normal operating conditions. Local exhaust ventilation may be required in specific circumstances.
Clear liquid with a mild odour; miscible with water.
Mixes with water.
| State | LIQUID | Molecular Weight | Not applicable |
| Melting Range (ºC) | Not available | Viscosity | Not Available |
| Boiling Range (ºC) | >100 | Solubility in water (g/L) | Miscible |
| Flash Point (ºC) | >100 (TCC) | pH (1% solution) | Not applicable |
| Decomposition Temp (ºC) | Not Available | pH (as supplied) | Not applicable |
| Autoignition Temp (ºC) | 421 | Vapour Pressure (kPa) | >1 |
| Upper Explosive Limit (%) | 12.6 | Specific Gravity (water=1) | 1.00-1.04 |
| Lower Explosive Limit (%) | 2.6 | Relative Vapour Density (air=1) | >1 |
| Volatile Component (%vol) | Not available | Evaporation Rate | Not available |
| propylene glycol | |
| ■ log Kow (Prager 1995): | - 0.92 |
| ■ log Kow (Sangster 1997): | - 0.92 |
· Presence of incompatible materials.
· Product is considered stable.
· Hazardous polymerisation will not occur.
For incompatible materials - refer to Section 7 - Handling and Storage.
| ACUTE HEALTH EFFECTS | CHRONIC HEALTH EFFECTS |
| ■ Harmful by inhalation and in contact with skin. | ■ May cause SENSITISATION by skin contact. |
| ■ Irritating to eyes and skin. | |
| ■ Vapours may cause dizziness or suffocation. |
2- OCTYL- 4- ISOTHIAZOLIN- 3- ONE: PROPYLENE GLYCOL: ■ unless otherwise specified data extracted from RTECS - Register of Toxic Effects of Chemical Substances. ■ unless otherwise specified data extracted from RTECS - Register of Toxic Effects of Chemical Substances.
| TOXICITY | IRRITATION |
| Oral (rat) LD50: 20000 mg/kg | Skin(human):500 mg/7days Mild |
| Dermal (rabbit) LD50: 20800 mg/kg | Skin(human):104 mg/3d Intermit Moderate |
| Dermal (rabbit) LD50: 11890 mg/kg | Eye (rabbit): 100 mg - Mild |
| Eye (rabbit): 500 mg/24h - Mild |
| TOXICITY | IRRITATION |
| Oral (rat) LD50: 550 mg/kg | Skin (rabbit): 500 mg/24 hours |
| Dermal (rabbit) LD50: 690 mg/kg | Eye(rabbit):100 mg SEVERE |
| Oral (male) rat: LD50 248 mg/kg | Skin (rabbit): 45% conc SEVERE |
| Oral (female) rat: LD50 293 mg/kg | Eye (rabbit): 45% conc CORROSIVE |
| Dermal (male) rabbit: LD50 311 mg/kg | Eye (rabbit): 5% conc Moderate |
| Eye (rabbit): 0.5% non Irritant |
Toxic to aquatic organisms, may cause long- term adverse effects in the aquatic environment. This material and its container must be disposed of as hazardous waste. Avoid release to the environment. Refer to special instructions/ safety data sheets.
| Ingredient | Persistence: Water/Soil | Persistence: Air | Bioaccumulation | Mobility |
| propylene glycol | LOW | LOW | HIGH | |
| 2-octyl-4-isothiazolin-3-one | HIGH | LOW | MED |
Name / EHS TRN A1a A1b A1 A2 B1 B2 C1 C2 C3 D1 D2 D3 E1 E2 E3 Cas No / RTECS No _________ ___ ___ ___ ___ ___ ___ ___ ___ ___ ___ ___ ___ ___ ___ ___ ___ ___ E1:_INTER 120 626 0 NI 0 R 0 0 0 0 (1) 0 1 D 1 F~ / 2 TY2000000
Legend:
EHS=EHS Number (EHS=GESAMP Working Group on the Evaluation of the Hazards of Harmful Substances Carried by Ships) NRT=Net Register Tonnage, A1a=Bioaccumulation log Pow, A1b=Bioaccumulation BCF, A1=Bioaccumulation, A2=Biodegradation, B1=Acuteaquatic toxicity LC/ECIC50 (mg/l), B2=Chronic aquatic toxicity NOEC (mg/l), C1=Acute mammalian oral toxicity LD50 (mg/kg), C2=Acutemammalian dermal toxicity LD50 (mg/kg), C3=Acute mammalian inhalation toxicity LC50 (mg/kg), D1=Skin irritation & corrosion, D2=Eye irritation& corrosion, D3=Long-term health effects, E1=Tainting, E2=Physical effects on wildlife & benthic habitats, E3=Interference with coastal amenities,
For column A2: R=Readily biodegradable, NR=Not readily biodegradable.
For column D3: C=Carcinogen, M=Mutagenic, R=Reprotoxic, S=Sensitising, A=Aspiration hazard, T=Target organ systemic toxicity, L=Lunginjury, N=Neurotoxic, I=Immunotoxic.
For column E1: NT=Not tainting (tested), T=Tainting test positive.
For column E2: Fp=Persistent floater, F=Floater, S=Sinking substances.
The numerical scales start from 0 (no hazard), while higher numbers reflect increasing hazard.
(GESAMP/EHS Composite List of Hazard Profiles - Hazard evaluation of substances transported by ships)
· Containers may still present a chemical hazard/ danger when empty.
· Return to supplier for reuse/ recycling if possible.
Otherwise:
· If container can not be cleaned sufficiently well to ensure that residuals do not remain or if the container cannot be used to store the same product, then puncture containers, to prevent re-use, and bury at an authorised landfill.
· Where possible retain label warnings and MSDS and observe all notices pertaining to the product.
Legislation addressing waste disposal requirements may differ by country, state and/ or territory. Each user must refer to laws operating in their area.
A Hierarchy of Controls seems to be common - the user should investigate:
· Reduction.
· DO NOT allow wash water from cleaning or process equipment to enter drains.
· It may be necessary to collect all wash water for treatment before disposal.
· In all cases disposal to sewer may be subject to local laws and regulations and these should be considered first.
· Where in doubt contact the responsible authority.
· Recycle wherever possible or consult manufacturer for recycling options.
· Consult State Land Waste Authority for disposal.
· Bury or incinerate residue at an approved site.
· Recycle containers if possible, or dispose of in an authorised landfill.
■ Environmentally Hazardous Substances meeting the descriptions of UN 3077 or UN 3082
are not subject to this Code when transported by road or rail in;
(a) packagings;
(b) IBCs; or
(c) any other receptacle not exceeding 500 kg(L).
- Australian Special Provisions (SP AU01) - ADG Code 7th Ed.
Labels Required: MISCELLANEOUS
●3Z (ADG7)
| Class or division: | 9 | Subsidiary risk: | None |
| UN No.: | 3082 | UN packing group: | III |
| Special provisions: | 274; 331; 335 | Packing Instructions: | None |
| Limited quantities: | 5 L | Portable tanks and bulk containers - Instructions: | T4 |
| Portable tanks and bulk containers - Special provisions: | TP1; TP29 | Packagings and IBCs - Packing instruction: | P001; IBC03; LP01 |
| Packagings and IBCs - Special packing provisions: | PP1 |
| Class or division: | 9 | Subsidiary risk: | None |
| UN No.: | 3082 | UN packing group: | III |
| ICAO/IATA Class: | 9 | ICAO/IATA Subrisk: | None |
| UN/ID Number: | 3082 | Packing Group: | III |
| Special provisions: | A97 | ||
| IMDG Class: | 9 | IMDG Subrisk: | None |
| UN Number: | 3082 | Packing Group: | III |
| EMS Number: | F-A , S-F | Special provisions: | 179 274 335 909 |
| Limited Quantities: | 5 L |
GESAMP hazard profiles for this material can be found in section 12 of the MSDS.
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Regulations for ingredients
"Australia Exposure Standards","Australia Hazardous Substances","Australia High Volume Industrial Chemical List (HVICL)","Australia Inventory of Chemical Substances (AICS)","GESAMP/EHS Composite List - GESAMP Hazard Profiles","IMO IBC Code Chapter 18: List of products to which the Code does not apply","IMO MARPOL 73/78 (Annex II) - List of Other Liquid Substances","International Council of Chemical Associations (ICCA) - High Production Volume List","OECD Representative List of High Production Volume (HPV) Chemicals"
"Australia ADI list - Acceptable daily intakes for agricultural and veterinary chemicals","Australia Hazardous Substances","Australia Inventory of Chemical Substances (AICS)","Australia Standard for the Uniform Scheduling of Drugs and Poisons (SUSDP) - Appendix E (Part 2)","Australia Standard for the Uniform Scheduling of Drugs and Poisons (SUSDP) - Schedule 6"
■ Classification of the preparation and its individual components has drawn on official and authoritative sources as well as independent review by the Chemwatch Classification committee using available literature references.
A list of reference resources used to assist the committee may be found at:
www.chemwatch.net/references.
■ The (M)SDS is a Hazard Communication tool and should be used to assist in the Risk Assessment. Many factors determine whether the reported Hazards are Risks in the workplace or other settings.
This document is copyright. Apart from any fair dealing for the purposes of private study, research, review or
criticism, as permitted under the Copyright Act, no part may be reproduced by any process without written
permission from CHEMWATCH. TEL (+61 3) 9572 4700.
Issue Date: 27-Feb-2009
Print Date: 24-Aug-2010
This is the end of the MSDS.