SOLVER 4130 PAVING PAINT COLOURS MCRLF
Chemwatch Independent Material Safety Data Sheet
Issue Date: 24-Jan-2006
C9317EC
CHEMWATCH 12307
Version No:3
SOLVER 4130 PAVING PAINT COLOURS MCRLF
"gloss alkyd paint coating"
PAINT
An exterior interior paving paint for application by brush, or hand roller.
Company: Solver Paints Pty Ltd
Address:
560 Churchill Road
Kilburn
SA, 5084
Australia
Telephone: +61 8 8368 1200
Emergency Tel: 1800 039 008 (24 hours)
Emergency Tel: +61 3 9573 3112
Fax: +61 8 8368 1222
HAZARDOUS SUBSTANCE. DANGEROUS GOODS. According to NOHSC Criteria, and ADG Code.
S5
Risk Codes Risk Phrases
R10 • Flammable.
R38 • Irritating to skin.
R48/20 • Harmful: danger of serious damage to health by prolonged
exposure through inhalation.
R52 • Harmful to aquatic organisms.
R63(3) • Possible risk of harm to the unborn child.
R65 • HARMFUL- May cause lung damage if swallowed.
R67 • Vapours may cause drowsiness and dizziness.
Safety Codes Safety Phrases
S36 • Wear suitable protective clothing.
S401 • To clean the floor and all objects contaminated by this
material use water and detergent.
S13 • Keep away from food drink and animal feeding stuffs.
S46 • If swallowed IMMEDIATELY contact Doctor or Poisons
Information Centre. (show this container or label).
S60 • This material and its container must be disposed of as
hazardous waste.
| NAME | CAS RN | % |
| mineral turpentine | Not avail. | 10-30 |
| white spirit | 8052-41-3. | 10-30 |
| colour pigments lead free typically | ||
| titanium dioxide | 13463-67-7 | 10-30 |
| additives, including lead free driers, | < 1.0 | |
| anti skinning agent, dispersing agent | ||
| alkyd resin solution | Various | 30-60 |
| NOTE: Manufacturer has supplied full ingredient | ||
| information to allow CHEMWATCH assessment. |
· If spontaneous vomiting appears imminent or occurs, hold patient's head down, lower than their hips to help avoid possible aspiration of vomitus.
· Avoid giving milk or oils.
· Avoid giving alcohol.
• If this product comes in contact with the eyes:
· Wash out immediately with fresh running water.
· Ensure complete irrigation of the eye by keeping eyelids apart and away from eye and moving the eyelids by occasionally lifting the upper and lower lids.
· Seek medical attention without delay; if pain persists or recurs seek medical attention.
· Removal of contact lenses after an eye injury should only be undertaken by skilled personnel.
• If skin contact occurs:
· Immediately remove all contaminated clothing, including footwear.
· Flush skin and hair with running water (and soap if available).
· Seek medical attention in event of irritation.
· If fumes or combustion products are inhaled remove from contaminated area.
· Lay patient down. Keep warm and rested.
· Prostheses such as false teeth, which may block airway, should be removed, where possible, prior to initiating first aid procedures.
· Apply artificial respiration if not breathing, preferably with a demand valve resuscitator, bag-valve mask device, or pocket mask as trained. Perform CPR if necessary.
• Treat symptomatically. Any material aspirated during vomiting may produce lung injury. Therefore emesis should not be induced mechanically or pharmacologically. For acute or short term repeated exposures to petroleum distillates or related hydrocarbons: · Primary threat to life, from pure petroleum distillate ingestion and/or inhalation, is respiratory failure. · Patients should be quickly evaluated for signs of respiratory distress (e.g. cyanosis, tachypnoea, intercostal retraction, obtundation) and given oxygen. Patients with inadequate tidal volumes or poor arterial blood gases (pO2 50 mm Hg) should be intubated. · Arrhythmias complicate some hydrocarbon ingestion and/or inhalation and electrocardiographic evidence of myocardial injury has been reported; intravenous lines and cardiac monitors should be established in obviously symptomatic patients. The lungs excrete inhaled solvents, so that hyperventilation improves clearance. · A chest x-ray should be taken immediately after stabilisation of breathing and circulation to document aspiration and detect the presence of pneumothorax.
· Foam. · Dry chemical powder. · BCF (where regulations permit). · Carbon dioxide.
· Alert Fire Brigade and tell them location and nature of hazard. · May be violently or explosively reactive. · Wear breathing apparatus plus protective gloves. · Prevent, by any means available, spillage from entering drains or water course. When any large container (including road and rail tankers) is involved in a fire, consider evacuation by 500 metres in all directions.
· Liquid and vapour are flammable. · Moderate fire hazard when exposed to heat or flame. · Vapour forms an explosive mixture with air. · Moderate explosion hazard when exposed to heat or flame. Combustion products include: carbon dioxide (CO2), nitrogen oxides (NOx), other pyrolysis products typical of burning organic material. Contains low boiling substance: Closed containers may rupture due to pressure buildup under fire conditions.
· Avoid contamination with oxidising agents i.e. nitrates, oxidising acids, chlorine bleaches, pool chlorine etc. as ignition may result.
•3Y
| Glasses: | Gloves: | Respirator: |
| Chemical goggles. | PVC chemical resistant type. | Type A-P Filter of sufficient capacity |
· Remove all ignition sources. · Clean up all spills immediately. · Avoid breathing vapours and contact with skin and eyes. · Control personal contact by using protective equipment.
· Clear area of personnel and move upwind. · Alert Fire Brigade and tell them location and nature of hazard. · May be violently or explosively reactive. · Wear breathing apparatus plus protective gloves.
Personal Protective Equipment advice is contained in Section 8 of the MSDS.
• Contains low boiling substance:
Storage in sealed containers may result in pressure buildup causing violent rupture of containers not rated appropriately.
· Check for bulging containers.
· Vent periodically
· Always release caps or seals slowly to ensure slow dissipation of vapours.
· Avoid all personal contact, including inhalation.
· Wear protective clothing when risk of overexposure occurs.
· Use in a well-ventilated area.
· Prevent concentration in hollows and sumps.
· DO NOT allow clothing wet with material to stay in contact with skin.
· Packing as supplied by manufacturer.
· Plastic containers may only be used if approved for flammable liquid.
· Check that containers are clearly labelled and free from leaks.
· For low viscosity materials (i) : Drums and jerry cans must be of the non-removable head type. (ii) : Where a can is to be used as an inner package, the can must have a screwed enclosure.
· For materials with a viscosity of at least 2680 cSt. (23 deg. C)
· For manufactured product having a viscosity of at least 250 cSt. (23 deg. C)
· Manufactured product that requires stirring before use and having a viscosity of at least 20 cSt (25 deg. C).
· Avoid reaction with oxidising agents.
· Store in original containers in approved flammable liquid storage area.
· Store away from incompatible materials in a cool, dry, well-ventilated area.
· DO NOT store in pits, depressions, basements or areas where vapours may be trapped.
· No smoking, naked lights, heat or ignition sources.
| Source | Material | TWA mg/m³ | Notes |
| ___________ | ___________ | _______ | _______ |
| Australia Exposure Standards | mineral turpentine (White spirits) | 790 | (see Chapter 16) |
| Australia Exposure Standards | mineral turpentine (Petrol (gasoline)) | 900 | (see Chapter 16) |
| Australia Exposure Standards | white spirit (White spirits) | 790 | (see Chapter 16) |
| Australia Exposure Standards | white spirit (Petrol (gasoline)) | 900 | (see Chapter 16) |
| Australia Exposure Standards | titanium dioxide (Titanium dioxide (a)) | 10 | (see Chapter 14) |
Type A-P Filter of sufficient capacity
· Safety glasses with side shields. · Chemical goggles. · Contact lenses may pose a special hazard; soft contact lenses may absorb and concentrate irritants. A written policy document, describing the wearing of lens or restrictions on use, should be created for each workplace or task. This should include a review of lens absorption and adsorption for the class of chemicals in use and an account of injury experience. Medical and first-aid personnel should be trained in their removal and suitable equipment should be readily available. In the event of chemical exposure, begin eye irrigation immediately and remove contact lens as soon as practicable. Lens should be removed at the first signs of eye redness or irritation - lens should be removed in a clean environment only after workers have washed hands thoroughly. [CDC NIOSH Current Intelligence Bulletin 59].
· Wear chemical protective gloves, eg. PVC. · Wear safety footwear or safety gumboots, eg. Rubber.
· Overalls. · PVC Apron. · PVC protective suit may be required if exposure severe. · Eyewash unit.
• For flammable liquids and flammable gases, local exhaust ventilation or a process enclosure ventilation system may be required. Ventilation equipment should be explosion-resistant. Air contaminants generated in the workplace possess varying "escape" velocities which, in turn, determine the "capture velocities" of fresh circulating air required to effectively remove the contaminant.
| Type of Contaminant: | Air Speed: |
| solvent, vapours, degreasing etc., evaporating from tank (in still air). | 0.25-0.5 m/s (50-100 f/min.) |
| aerosols, fumes from pouring operations, intermittent container filling, low speed conveyer transfers, welding, spray drift, plating acid fumes, pickling (released at low velocity into zone of active generation) | 0.5-1 m/s (100-200 f/min.) |
| direct spray, spray painting in shallow booths, drum filling, conveyer loading, crusher dusts, gas discharge (active generation into zone of rapid air motion) | 1-2.5 m/s (200-500 f/min.) |
Coloured flammable liquid coating; does not mix with water. Mild solvent odour.
Liquid.
Does not mix with water.
| State | Liquid | Molecular Weight | Not applicable. |
| Melting Range (ºC) | Not available. | Viscosity | Not available |
| Boiling Range (ºC) | 140-200 approx | Solubility in water (g/L) | Insoluble |
| Flash Point (ºC) | 35 | pH (1% solution) | Not applicable. |
| Decomposition Temp (ºC) | Not available | pH (as supplied) | Not applicable |
| Autoignition Temp (ºC) | Not available. | Vapour Pressure (kPa) | As min. turps |
| Upper Explosive Limit (%) | 3.6 min.turps | Specific Gravity (water=1) | 0.9-1.2 approx |
| Lower Explosive Limit (%) | 0.5 min.turps. | Relative Vapour Density (air=1) | >1 |
| Volatile Component (%vol) | 30-50 approx. | Evaporation Rate | Slow |
· Presence of incompatible materials.
· Product is considered stable.
· Hazardous polymerisation will not occur.
For incompatible materials - refer to Section 7 - Handling and Storage.
| ACUTE HEALTH EFFECTS | CHRONIC HEALTH EFFECTS |
| • Irritating to skin. | • Possible risk of harm to the unborn child. |
| • HARMFUL-May cause lung damage if swallowed. | • Harmful: danger of serious damage to health by prolonged exposure through inhalation. |
| • Vapours may cause dizziness or suffocation. | |
| • Vapours may cause drowsiness and dizziness. |
WHITE SPIRIT: TITANIUM DIOXIDE: MINERAL TURPENTINE: • unless otherwise specified data extracted from RTECS - Register of Toxic Effects of Chemical Substances. WHITE SPIRIT: MINERAL TURPENTINE: • for petroleum: This product contains benzene which is known to cause acute myeloid leukaemia and n-hexane which has been shown to metabolize to compounds which are neuropathic. This product contains toluene. This product contains ethyl benzene and naphthalene from which there is evidence of tumours in rodents Carcinogenicity: Inhalation exposure to mice causes liver tumours, which are not considered relevant to humans. • Not available. Refer to individual constituents. MINERAL TURPENTINE:
| TOXICITY | IRRITATION |
| Inhalation (human) TCLo: 600 mg/m³/8h | Nil Reported |
| Oral (rat) LD50: >5000 mg/kg | Eye (human): 470 ppm/15m |
| Inhalation (rat) LC50: >5500 mg/m³/4h | Eye (rabbit): 500 mg/24h Moderate |
| TOXICITY | IRRITATION |
| Oral (Rat) LD50: >20000 mg/kg * | Skin (human): 0.3 mg /3D (int)-Mild * |
| Oral (Mouse) LD50: >10000 mg/kg * |
| Gasoline (NB: Overall evaluation upgraded from 3 to 2B with supporting evidence from other relevant data) | International Agency for Research on Cancer (IARC) - Agents Reviewed by the IARC Monographs | Group | 2B |
| Crude oil | International Agency for Research on Cancer (IARC) - Agents Reviewed by the IARC Monographs | Group | 3 |
| Titanium dioxide | International Agency for Research on Cancer (IARC) - Agents Reviewed by the IARC Monographs | Group | 2B |
Harmful to aquatic organisms. This material and its container must be disposed of as hazardous waste.
| Ingredient | Persistence: Water/Soil | Persistence: Air | Bioaccumulation | Mobility |
| titanium dioxide | HIGH | LOW | HIGH |
· Recycle wherever possible.
· Consult manufacturer for recycling options or consult local or regional waste management authority for disposal if no suitable treatment or disposal facility can be identified.
· Dispose of by: burial in a land-fill specifically licenced to accept chemical and / or pharmaceutical wastes or Incineration in a licenced apparatus (after admixture with suitable combustible material).
· Decontaminate empty containers. Observe all label safeguards until containers are cleaned and destroyed.
Labels Required: FLAMMABLE LIQUID
•3Y (ADG7)
| Class or division: | 3 | Subsidiary risk: | None |
| UN No.: | 1263 | UN packing group: | III |
| Special provisions: | 163; 223 | Packing Instructions: | None |
| Limited quantities: | 5 L | Portable tanks and bulk containers - Instructions: | T2 |
| Portable tanks and bulk containers - Special provisions: | TP1; TP29 | Packagings and IBCs - Packing instruction: | P001; IBC03; LP01 |
| Packagings and IBCs - Special packing provisions: | PP1 |
| Class or division: | 3 | Subsidiary risk: | None |
| UN No.: | 1263 | UN packing group: | III |
| ICAO/IATA Class: | 3 | ICAO/IATA Subrisk: | None |
| UN/ID Number: | 1263 | Packing Group: | III |
| Special provisions: | A3 | ||
| IMDG Class: | 3 | IMDG Subrisk: | None |
| UN Number: | 1263 | Packing Group: | III |
| EMS Number: | F-E , S-E | Special provisions: | 163 223 955 |
| Limited Quantities: | 5 L |
S5
Regulations for ingredients
"Australia Exposure Standards","Australia Hazardous Substances","Australia Inventory of Chemical Substances (AICS)","Australia Standard for the Uniform Scheduling of Drugs and Poisons (SUSDP) - Appendix E (Part 2)","GESAMP/EHS Composite List - GESAMP Hazard Profiles","IMO IBC Code Chapter 17: Summary of minimum requirements","IMO Provisional Categorization of Liquid Substances - List 2: Pollutant only mixtures containing at least 99% by weight of components already assessed by IMO","International Council of Chemical Associations (ICCA) - High Production Volume List","OECD Representative List of High Production Volume (HPV) Chemicals"
"Australia Exposure Standards","Australia High Volume Industrial Chemical List (HVICL)","Australia Inventory of Chemical Substances (AICS)","Australia Therapeutic Goods Administration (TGA) Substances that may be used as active ingredients in Listed medicines","Australia Therapeutic Goods Administration (TGA) Sunscreening agents permitted as active ingredients in listed products","CODEX General Standard for Food Additives (GSFA) - Additives Permitted for Use in Food in General, Unless Otherwise Specified, in Accordance with GMP","GESAMP/EHS Composite List - GESAMP Hazard Profiles","IMO IBC Code Chapter 17: Summary of minimum requirements","International Agency for Research on Cancer (IARC) - Agents Reviewed by the IARC Monographs","OECD Representative List of High Production Volume (HPV) Chemicals"
No data for mineral turpentine (CAS: , Not avail)
No data for alkyd resin solution (CAS: , Various)
| Ingredient Name | CAS |
| white spirit | 8052-41-3, 8042-47-5 |
| titanium dioxide | 13463-67-7, 1317-70-0, 1317-80-2, 12188-41-9, 1309-63-3, 100292-32-8, 101239-53-6, 116788-85-3, 12000-59-8, 12701-76-7, 12767-65-6, 12789-63-8, 1344-29-2, 185323-71-1, 185828-91-5, 188357-76-8, 188357-79-1, 195740-11-5, 221548-98-7, 224963-00-2, 246178-32-5, 252962-41-7, 37230-92-5, 37230-94-7, 37230-95-8, 37230-96-9, 39320-58-6, 39360-64-0, 39379-02-7, 416845-43-7, 494848-07-6, 494848-23-6, 494851-77-3, 494851-98-8, 55068-84-3, 55068-85-4, 552316-51-5, 62338-64-1, 767341-00-4, 97929-50-5, 98084-96-9 |
• Classification of the preparation and its individual components has drawn on official and authoritative sources as well as independent review by the Chemwatch Classification committee using available literature references.
A list of reference resources used to assist the committee may be found at:
www.chemwatch.net/references.
• The (M)SDS is a Hazard Communication tool and should be used to assist in the Risk Assessment. Many factors determine whether the reported Hazards are Risks in the workplace or other settings.
This document is copyright. Apart from any fair dealing for the purposes of private study, research, review or
criticism, as permitted under the Copyright Act, no part may be reproduced by any process without written
permission from CHEMWATCH. TEL (+61 3) 9572 4700.
Issue Date: 24-Jan-2006
Print Date: 6-Aug-2010
This is the end of the MSDS.